phototriggered base proliferation reaction, which integrated the safety and strong penetrating ability of UV photopolymerization as well as Domino free radical photopolymerization based on phototriggered base proliferation reaction, is expected to expand the application of thiol-ene Michael addition reaction....
The Michael addition-like thiol–ene reaction is a useful tool that can be used to tag proteins with high selectivity for the solvent-exposed thiol groups of proteins. To obtain insight into the bioconjugation of proteins with this method, a kinetic analysis was performed. New vinyl-substituted ...
Thekey attribute of the thiol-Michael addition reaction that makesit a prized tool in materials science is its modular "click"nature, which allows for the implementation of this highly efficient,"green" reaction in applications that vary from smallmolecule synthesis to in situ polymer modifications ...
Multivalent Functional-ization of Cyclodextrins by Photochemical Thiol-Ene Ad-dition Reaction[J]. European Journal of Organic Chemis-try,2013,2013(30): 6831-6843.Multivalent Functionalization of Cyclodextrins by Photochemical Thiol‐Ene Addition Reaction[J] . Maria M. Becker,Zhaoyang Zeng,Bart Jan ...
2.2.2. Thiol-Michael addition A less common approach to the modification of polypeptides is the use of thiol-Michael addition reactions. This type of reaction is very common for small molecule or other types of polymer systems, but less typical for the main-chain functionalization of polypeptides...
通过巯烯反应(thiol-ene reaction), MimMP上的巯基与SBR分子发生反应,且反应的位置主要是SBR中的端双键。MimMP因与silic…cdmd.cnki.com.cn|基于1 个网页 2. 加成反应 首次引入巯基与双键加成反应(Thiol-ene reaction),分别采用"grafting-from"和"grafting-onto"的方法实现对正辛基联烯/苯乙烯共聚 …cdmd.cnki...
N. A new photoclick reaction strategy: photo-induced catalysis of the thiol-Michael addition via a caged primary amine. Chem. Commun. 49, 4504-4506 (2013).A new photoclick reaction strategy:photo-induced catalysis of the thiol-Michael addition via a caged primary amine. Xi W,Krieger M,Klox...
Upon addition of tris (2-carboxyethyl) phosphine, the thiol-ene Michael addition reaction between GSH and AA was efficiently catalyzed, resulted in the quenched fluorescence triggered on. Under the optimum conditions, a linear detection range from 0.1 to 104μM was implemented for AA with a ...
YOU YeZi CAS Key Lab of Soft Matter Chemistry;Department of Polymer Science and Engineering,University of Science and Technology of China,Hefei 230026,China.One-pot synthesis of hyperbranched poly(amido amine) clicked with a sugar shell via Michael addition polymerization and thiol click reaction[J]...
Lastly, spatiotemporal control of both the thiol-ene reaction and thiol-Michael addition reaction were utilized to form a material with patterned functionalities and material properties, starting from a mixture of multifunctional thiols and an excess of multifunctional acrylates. This approach is based ...