This discussion also covers how an initiator works and its effect on the reaction rate. Moreover, the utilization of thiol–ene reactions for the synthesis of terpene-based valuable platform chemicals, monomers, and polymers, including recent examples that demonstrate its broad utility, are ...
Thiol–ene "click" chemistry has emerged as a powerful strategy to construct carbon–heteroatom (CS) bonds, which generally results in the formation of two regioisomers. To this end, the neutral ionic liquid [hmim]Br has been explored as a solvent cum catalyst for the synthesis of linear ...
However, the thiol-ene reaction has recently attracted researchers in other areas of synthesis due to the recognition of its ‘‘click’’ characteristics, vide infra. There are several features associated with the thiol-ene reaction that make it a particularly ...
然后通过研究硫醇功能化CNC与丁晴橡胶基体之间的界面相容性和相互作用,讨论了纳米复合材料在梯度硫醇化下的热性能和力学性能,并通过相互作用研究揭示了其增强机理。这一研究成果以题为“Covalent-bond-forming method to reinforce rubber with cellulose nanocrystal based on the thiol-ene click reaction”发表于Composit...
Optothermal responsive polymersPoly (N-isopropylacrylamide)Thiol-ene click reactionAggregation behaviorThermosensitive and photosensitive polymers (PNIPAM-Azo) were synthesized by thiol-ene click reaction with PNIPAM with terminal thiol groups (PNIPAM-SH) and azobenzene compounds containing a double bond. ...
这一研究成果以题为“Covalent-bond-forming method to reinforce rubber with cellulose nanocrystal based on the thiol-ene click reaction”发表于Composites Communications期刊。 图1. 硫醇化CNC及其复合材料的制备 图2. (a)不同mCNC3含量的交联密度;(b) mCNC3:不同辐照时间下交联密度;第二次加热的差示量热...
thiol-enereaction网络巯烯反应;加成反应 网络释义 1. 巯烯反应 通过巯烯反应(thiol-ene reaction), MimMP上的巯基与SBR分子发生反应,且反应的位置主要是SBR中的端双键。MimMP因与silic…cdmd.cnki.com.cn|基于1 个网页 2. 加成反应 首次引入巯基与双键加成反应(Thiol-ene reaction),分别采用"grafting-from"和...
The reaction was performed under mild conditions to yield rGO functionalized with the dopamine derivative. The chemical reactivity of the alkynyl function was demonstrated by post-functionalization with two thiolated precursors, namely 6-(ferrocenyl)hexanethiol and 1H,1H,2H,2H-perfluorodecanethiol. X-...
Superhydrophobic PA66 was obtained with plant derived phenols by thiol-ene click chemistry reaction.pCA-Fe-PA66 is self-cleaning, UV-blocking, photothermal conversion and antibacterial.The preparation method is mild, fast, simple, and expands the application of phenols.Prepared fabric has potential in...
Diallyl eugenol(2A-EU)and tetrathioglycoluril(TMGU)were prepared from eugenol and glycoluril,respectively. A series of thiol-ene UV curable coatings was prepared by adjusting n(2A-EU)∶n(TMGU), and their heat resistance,curin