The thiol-Michael addition 'click' reaction has numerous advantageous characteristics for polymerization reactions, such as having a high reaction rate and yield under mild reaction conditions without the formation of byproducts, starting from a large selection of easily accessible monomers. Firstly, ...
Thekey attribute of the thiol-Michael addition reaction that makesit a prized tool in materials science is its modular "click"nature, which allows for the implementation of this highly efficient,"green" reaction in applications that vary from smallmolecule synthesis to in situ polymer modifications ...
The organic/inorganic hybrid material of poly[2-(dimethyl amino)-ethyl methacrylate]/polyhedral oligomeric silsesquioxane (POSS-PDMAEMA) was synthesized via a thiol-Michael addition reaction. The structures of POSS-PDMAEMA and its self-assembly in aqueous solution were confirmed by H-1-NMR, TEM, ...
6. Visible-Light-Initiated Thiol-Michael Addition Polymerizations with Coumarin-Based Photobase Generators: Another Photoclick Reaction Strategy [O] . Xinpeng Zhang, Weixian Xi, Chen Wang, -1 机译:可见光引发的Thiol-Michael加成聚合与基于香豆素的光引发剂:另一种photoclick反应策略 7. Visible-Light...
ChemInform Abstract: Thiol-Mediated Tandem Michael—Aldol Reaction: A Convenient Method for the Synthesis of Fused Cyclopentenonesindan derivativescycloaddition reactionsbenzofuran derivativesEsters of type (I) bearing a formyl group are treated with methyl thioglycolate in order to get thiopyrans of type...
Simple Plate-Based, Parallel Synthesis of Disulfide Fragments using the CuAAC Click Reaction Disulfide exchange screening is a site-directed approach to fragment-based lead discovery that requires a bespoke library of disulfide-containing fragments... DM Turner,CTMB Tom,AR Renslo - 《Acs ...
Then, the functional monomer vinyl azlactone (VDM) was quantitatively 鈥渃licked鈥onto the chain end using a thiol-Michael addition reaction. The polymers were reacted with a model amine in order to demonstrate the potential of these polymers for bioconjugation. 展开 ...
Upon addition of tris (2-carboxyethyl) phosphine, the thiol-ene Michael addition reaction between GSH and AA was efficiently catalyzed, resulted in the quenched fluorescence triggered on. Under the optimum conditions, a linear detection range from 0.1 to 104μM was implemented for AA with a ...
YOU YeZi CAS Key Lab of Soft Matter Chemistry;Department of Polymer Science and Engineering,University of Science and Technology of China,Hefei 230026,China.One-pot synthesis of hyperbranched poly(amido amine) clicked with a sugar shell via Michael addition polymerization and thiol click reaction[J]...
hydrogel;reaction kinetics;mechanical homogeneity;peptide 3. Conclusions In summary, we demonstrated a new kind of method to prepare homogeneous poly(ethylene glycol) hydrogels based on Michael-type addition reaction using peptides with amino groups at the side chain. By adding the short peptides in...