Halogen bonding refers to the non-covalent interactions of halogen atoms X in some molecules, RX, with negative sites on others. It can be explained by the presence of a region of positive electrostatic potential, the σ-hole, on the outermost portion of the halogen's surface, centered on ...
英文名称:Pillar arenes Halogen-bonding 柱状芳烃卤素键合是指在柱状芳烃分子结构中引入卤素原子(如氟、氯、溴、碘等)与其他化合物形成共价键的化学反应。这种反应通常用于柱状芳烃的功能化改性,以赋予其新的化学性质或增强其在特定应用中的性能。结构特点 柱状芳烃分子:柱状芳烃是一种具有中空空腔结构的分子,...
In contrast, the use of halogen bonding to trigger supramolecular gel formation in a two-component gel (‘co-gel’) is essentially unexplored, and forms the basis for this study. Here, we show that halogen bonding between a pyridyl substituent in a bis(pyridyl urea) and 1,4-diiodo...
Halogen Bonding: From Self-Assembly to Materials and Biomolecules. CrystEngComm 2013, 15, 3057. [CrossRef]Pennington, W. T.; Resnati, G.; Taylor M. S.: Halogen bonding: from self- assembly to materials and biomolecules. CrystEngComm 15 (2013) 3057-3057 and articles of the related themed ...
Because of its expected applicability for modulation of molecular recognition phenomena in chemistry and biology, halogen bonding has lately attracted rapidly increasing interest. As most of these processes proceed in solution, the understanding of the i
Halogen bonding (XB), the attractive interaction between an electron-deficient halogen atom and a Lewis base, has undergone a dramatic development as an intermolecular force analogous to hydrogen bonding (HB). However, its utilization in the solution pha
Halogen Bonding 作者: Metrangolo, P. (EDT)/ Resnati, G. (EDT)/ Arman, H. D. (CON)/ Biella, S. (CON)/ Bruce, D. W. (CON) 页数: 221 定价: $ 303.97 ISBN: 9783540743293 豆瓣评分 目前无人评价 评价: 写笔记 写书评 加入购书单 分享到 推荐 内容简介 ··· This series ...
ICEPI: 16 应助: 385 (硕士) 贵宾: 1.832 金币: 78 散金: 12009 红花: 80 沙发: 5 帖子: 12361 在线: 551.8小时 虫号: 1229647 注册: 2011-03-11 性别: GG 专业: 有机合成[交流] 一个不错的课题,halogen bonding,很有趣,有兴趣可以看看已有...
Dynamic processes have many implications in functional molecules, including catalysts, enzymes, host-guest complexes, and molecular machines. Here, we demonstrate via deuterium NMR relaxation experiments how halogen bonding directly impacts the dynamics
Perspectives on halogen bonding and other σ-hole interactions: Lex parsimoniae (Occam's Razor). Comput. Theor. Chem. 2012, 998, 2-8.Politzer, P.; Riley, K.E.; Bulat, F.A.; Murray, J.S. Perspectives on halogen bonding and other σ-hole interactions: Lex parsimoniae (Occam's Razor...