anion recognitionanionshalogen bondinghost–guest systemssupramolecular chemistryThe halogen bond is a supramolecular interaction between a Lewis‐acidic region of a covalently bound halogen and a Lewis base. It has been studied widely insilico and experimentally in the solid state; however, solution‐...
Halogen bonding is the noncovalent interaction where the halogen atom acts as an electrophile towards Lewis bases. Known for more than 200 years, only recently it has attracted interest in the context of solution-phase applications, especially during the last decade which was marked by the introduct...
Herein, we use X-ray absorption spectroscopy to confirm halogen bonding can exist at the dye-electrolyte interface. Using a known series of triphenylamine-based dyes bearing halogen substituents geometrically positioned for reaction with halides in solution, halogen bonding was detected only in cases ...
Halogen bonding (XB), the attractive interaction between an electron-deficient halogen atom and a Lewis base, has undergone a dramatic development as an intermolecular force analogous to hydrogen bonding (HB). However, its utilization in the solution pha
O Hydrogen Bonds in Solution;立体效应促进的分子间C—H…O氢键 12.Spatial Configurations and Bonding Effects of NO_2 and N_2O_4;NO_2、N_2O_4分子的空间构型和键合作用 13.Weak bond interactions between H2O and HX(X=F,Cl,Br)H_2O与HX(X=F,Cl,Br)分子间弱键相互作用 14.Theoretical Study...
Halogen and hydrogen bonding were compared in the solid state, solution, and gas phase in three series of halogen-bonded complexes derived from p-substituted pyridine derivatives and 3 N-halosuccinimides (iodo-, bromo-, and chloro-; NIS, NBS, and NCS) and an equivalent series of hydrogen-...
Mechanism and application of halogen bond induced fluorescence enhancement and iodine molecule cleavage in solution.doi:10.1039/c4nj01396dIn this paper, a ... - 《New Journal of Chemistry》 被引量: 0发表: 2015年 Halogen bonding in solution Halogen bonding is the electron density donation based ...
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The formation of halogen-bonded cocrystals between tftib donor and PPh3, AsPh3, or SbPh3 contrasts the documented behavior of organophosphines and -arsines towards strong XB donor halogens and interhalogens, which usually results in covalent bonding between pnictogens and halogens25,27. Importantly...
D. in Halogen Bonding. Structure and Bonding (eds Metrangolo, P. & Resnati, G.) 65–104 (Springer, 2007). Zhou, F. et al. A new type of halogen bond involving multivalent astatine: an ab initio study. Phys. Chem. Chem. Phys. 21, 15310–15318 (2019). Article CAS PubMed Google...