Halogen bonding (XB) has been recently exploited as a significant tool for engineering crystals involving coordination and organometallic compounds as tectons. This review, in particular, focuses on extended networks based on XB between electron donor groups bound to metals and halo-pyridine and halo-...
Review Free Access Halogen bonding (X-bonding): A biological perspective Matthew R. Scholfield, Crystal M. Vander Zanden, Megan Carter, P. Shing Ho First published: 06 December 2012 https://doi.org/10.1002/pro.2201 Citations: 393 Sections PDF Tools Share Abstract The concept of the ...
In this review, we discuss the regioselective deiodination of THs by organochalcogen compounds. Naphthyl‐based compounds containing sulphur and/or selenium at the peri﹑ositions mediate regioselective 5ヾeiodination of THs and detailed mechanistic studies revealed that the heterolytic cleavage of C㊣ ...
Structure and Bonding (eds Metrangolo, P. & Resnati, G.) 65–104 (Springer, 2007). Zhou, F. et al. A new type of halogen bond involving multivalent astatine: an ab initio study. Phys. Chem. Chem. Phys. 21, 15310–15318 (2019). Article CAS PubMed Google Scholar Ji, X. A ...
Rational drug design of halogen-bonding lead molecules requires an accurate description of halocarbon-protein complexes by computational tools though not all methods are able to tackle this non-covalent interaction. Areas covered: The authors present a review of computational methodologies that can be ...
In this review, the important roles of halogen bonding, one of the fundamental noncovalent interactions, in enhancing room-temperature phosphorescence are outlined based on recent progresses in both experimental and theoretical studies on this topic. Brightened prospects for future design, preparation and...
Halogen bonding: a general route in anion recognition and coordinationPart of a themed issue on the supramolecular chemistry of anionic species.This critical reviewdescribes how halocarbons can function as effective binding sites of anions viahalogen bonding, the noncovalent interaction whereby halogen ...
Book Review of Halogen Bonding: Fundamentals and Applications. Structure and Bonding, 126 Halogen bonding is a highly directional noncovalent interaction between a covalently bonded halogen atom (usually Cl, Br, or I) and a negative site on another molecule or ion, e.g., a lone pair of a Le...
et al. Activation of glycosyl halides by halogen bonding. Chem. Asian J. 9, 2095–2098 (2014). Article CAS PubMed Google Scholar Kobayashi, Y., Nakatsuji, Y., Li, S., Tsuzuki, S. & Takemoto, Y. Direct N-glycofunctionalization of amides with glycosyl trichloroacetimidate by thiourea/...
Halogen bonding (XB), an attractive interaction between an electrophilic region on a halogen atom and a nucleophile1, has emerged as one of the most important directional intermolecular forces, relevant for the design of functional solids, separations, pharmaceuticals, biomolecular recognition and more2...