Under the similar conditions, the hydrolysis of N-acyl-3-amino-1-phenyl-1,2-dicarba-closo-dodecaboranes resulted in amide bond cleavage accompanied by simultaneous deboronation with the removal of boron atom at position 6 of carborane cage and formation of 7,8-dicarba-nido-undecaborane ...
amide formation, amide hydrolysisbridged compoundscarboxylic amides (benzene compounds)ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, ...
Complex anionic speciation of halometallate ionic liquids is reflected in the exemplary phase diagram for chloroaluminate(III) ILs (Fig.1). It is the speciation that dictates their physical properties and chemical behavior, including Lewis acidity. Organic cations are considered to affect physical prop...
Catalyzes the hydrolysis of the lipoyl cofactor, releasing free lipoic acid. A protein that catalyzes the ATP-dependent activation and transfer of lipoic acid to lipoyl carrier proteins. P-protein Subunit of the glycine cleavage system, which uses pyridoxal 5′-phosphate to catalyze the oxidative de...
Tricyclic Diester and 2,5-Furandicarboxylic Acid for the Synthesis of Biobased Hydrolysis Copolyesters with High Glass Transition Temperatures The reluctance of a polyester with high glass transition temperature (T-g) and mechanical properties to hydrolyze is a well-known fact, for instance, the h....
Efficient hydrolysis of chitosan in ionic liquids 热度: CHEM.RES.CHINESEUNIVERSITIES2010 ,26(3),384～388 BronstedAcidicIonicLiquids:NovelEfi cient,Cost—effectiveand ReusableSolvent—catalystsforRitterReaction JIANGFeng,LINYing-jie,DUANHai-feng,LIZong-han,CAOJun.gangandLIANGDa.peng ...
K suggests that at lower temperatures the hydrolysis of the ester product is only discouraged and the reversible reaction not fully eliminated. It is only at ambient or near-ambient temperatures that a Brønsted acidic ionic liquid catalysed reaction becomes appealing because of the effort required ...
A strain of Fusarium solani degrades metal-complexed cyanides under neutral and acidic pH conditions. Cyanide undergoes hydrolysis to formamide by cyanide... M Barclay,VA Tett,CJ Knowles - 《Enzyme & Microbial Technology》 被引量: 187发表: 1998年 Selective Preparation of SnO2 and SnO Crystals ...
from C12-18monoolefins having a terminal or internal double bond by sulfonating with gaseous sulfur trioxide followed by alkaline or acidic hydrolysis of the sulfonation products. Anionic surfactants that are preferred for use in the cleaning compositions of the present invention include the alkyl benz...
The reactions of the oxazolidine ring for HBDOZ occur about 10 times faster than those for MBDOZ and PBDOZ. For HBDOZ, hydrolysis of the amide bodn of the diazepine ring takes place rather than that of the iminium bond, in contrast to the cases of MBDOZs and PBDOZs. 展开 ...