During the past few decades, great efforts have been devoted to the design and self-assembly of discrete metal鈥搊rganic cages/containers (MOCs) with increasing complexity and functionality. Among which, the inc
High-pressure experiments performed on aperiodic TRUMOF-1 demonstrate that this material remains crystalline up to pressures of 1.8 GPa, higher than other cubic metal–organic framework, due to the heterogeneous distribution of different shock-absorption mechanisms throughout the material. ...
Interplay between defects, disorder and flexibility in metal-organic frameworks Nat. Chem., 9 (1) (Dec. 2016), pp. 11-16, 10.1038/nchem.2691 View in ScopusGoogle Scholar [68] Jorge Sotelo, Scott Mckellar, Stephen Moggach, John Mowat, Anna Warren, Mark Warren, Paul Wright In-situ Gas...
(+3.5%). Comparison of the crystal structures of1∙gand1showed that the conformation change of the organic ligand is responsible for the framework flexibility. The 3D intersecting channel occupies 48.4% volume of1, corresponding to a crystallographic pore volume of 0.513 cm3 g−1(...
magnetism, luminescence, optoelectronics, or photovoltaics exemplify some of their diverse applications1,2,3,4,5,6,7. The key to their success lies in a tuneable framework composed of metal cations coordinated by bridging ligands (organic or inorganic), with cavities occupied by rationally chosen ...
The examples included conformational flexibility of Ph–X–Ph (X = CH2, C=O, etc.) type molecules, nucleophilic addi- tion of nitrogen to a carbonyl group, SN2 substitution at silicon, and topochemical interconversion pathways in penta-coordinate complexes. Another set of joint analyses comparing...
A serial of hexagonal-prismatic metal organic cages (MOCs), [Co6(OH)2(HCOO)6(pbim)6(H2O)6]·SO4·2HCOO·8H2O (1·2HCOO·8H2O), [Ni6(OH)2(HCOO)6(pbim)6(H2O)6]·SO4·2HCOO·8H2O (2·HCOO·8H2O), {[Co6(μ3-OH)2(μ-HCOO)6(pbim)6(H2O)6]·ClO4}3+·3HCOO·...
Dative boron-nitrogen bonds in structural supramolecular chemistry: multicomponent assembly of prismatic organic cages. Chem. Sci. 2:1719-1721.Icli B, Solari E, Riis-Johannessen T, Schenk K, Filinchuk Y, Scopelliti R, Severin K (2011) Chem Sci 2:1719–1721 View Article...
Additionally, Ni-MOF nanomaterials have excellent flexibility, mechanical properties and high packing densities, resulting in high electrochemical properties by surface modification, intra-layer doping and lattice strain [36], [37], [38]. A preparation method for the formation of CoS2@NiS2 ...
The flexibility of the invention permits walls 12 to be erected one at a time consecutively, but it is preferable to erect temporary support systems for several adjacent walls 12 and then stack adjoining walls 12 simultaneously. Simultaneous erection of adjoining walls 12 (and their respective accom...