Nowadays, MOFs have attracted great scientific interest regarding their application as catalysts, mainly due to their porous 3D structures with large, regular, and accessible cages capable of incorporating catalytic active molecules with suitable shapes and sizes [67]. On the other hand, the pores ...
Shape assisted fabrication of fluorescent cages of squarate based metal–organic coordination frameworks. Chem. Commun. 2013, 49, 3937–3939. [Google Scholar] [CrossRef] [PubMed] Li, H.; Wang, J.; Zhai, Q. Development of MOF-5-like ultra-microporous metal-squarate frameworks for efficient ...
The zirconium-based MOF material UiO-66 is composed of octahedral and tetrahedral cages and has excellent thermal, aqueous, and acid stability [27,28,29]. Based on these advantages, UiO-66 has been used as a catalytic carrier of precious metals to detect H2O2and telomerase [30,31,32]. How...
Although MOF-808 has zirconium clusters similar to those of UiO-66, this structure is connected by the BTC binder and has two different hole cages of approximately 18 and 14 [118]. UiO-66 has a 7.5 Å tetrahedral cage and a 12 Å octahedral cage, with a pore opening of 6 Å ...