Metal–organic cages, a class of molecular containers formed via coordination-driven self-assembly, show great promise as separation agents. Precise control ofthe shape, size and functionalization of cage cavit
thus providing promising coordination frameworks by using the whole toolbox of organic chemistry. Different crystalline structures and intended modifications of organic linkers further lead to optimized adsorptive interactions or molecular diffusion through pore size control. For membranes, MOF films of <...
Metal–organic cages for molecular separations Nat Rev Chem, 5 (2021), pp. 168-182 CrossrefView in ScopusGoogle Scholar [15] S.-.M. Xie, N. Fu, L. Li, B.-.Y. Yuan, J.-.H. Zhang, Y.-.X. Li, et al. Homochiral metal–organic cage for gas chromatographic separations Anal Che...
2.2.2. Encapsulation in the cages Framework flexibility is ubiquitous and one of the most distinctive characters in MOF category, which brings about the breathing/gate-opening effect of MOF apertures and lessons the molecular sieve ability for gases with minimum size differences. The chemical PSM pr...
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In Metal-Organic Frameworks: Applications in Separations and Catalysis; García, H., Navalón, S., Eds.; Wile, 2018; Chapter 3; pp 57–80.10.1002/9783527809097.ch3Search in Google Scholar Found, C.; Helwig, K. The reliability of spot tests for the detection of arsenic and mercury in ...
Breakthrough curves for 1:1:1 pX/mX/oX separations with ZU-61 at 398 K (a), 333 K (b), and recycle performance at 398 K (c). Breakthrough separation of ternary mixture of pX, mX, oX. Breakthrough tests are efficient tools to screen suitable adsor- bents. The separation ability ...
Metal-organic frameworks can offer pore geometries that are not available in zeolites or other porous media, facilitating distinct types of shape-based molecular separations. Here, we report Fe2(BDP)3 (BDP2– = 1,4-benzenedipyrazolate), a highly stable framework with triangular channels that eff...
Metal organic framework mixed matrix membranes for gas separations. Microporous Mesoporous Mater. 131, 13–20 (2010). CAS Google Scholar Bavykina, A., Cadiau, A. & Gascon, J. Porous liquids based on porous cages, metal organic frameworks and metal organic polyhedra. Coord. Chem. Rev. 386...
The synthesis of mesoporous metal–organic frameworks (meso-MOFs) is desirable as these materials can be used in various applications. However, owing to the imbalance in structural tension at the micro-scale (MOF crystallization) and the meso-scales (ass