Metal–organic cages, a class of molecular containers formed via coordination-driven self-assembly, show great promise as separation agents. Precise control ofthe shape, size and functionalization of cage cavities enables them to selectively bind and distinguish a wide scope of physicochemically similar...
Metal-organic frameworks for separations. The cellular and molecular pharmacology of the new class of anticancer drugs, in which the CDK inhibitor bohemine and its analogues are coordinated to Pt(I... Li, Jian-Rong,J Sculley,Zhou, Hong-Cai - 《Chemical Reviews》 被引量: 2780发表: 2012年 ...
recovery from aqueous solutions by adsorption in metal– organic framework MIL-101: a molecular simulation study Krishna M. Gupta, Kang Zhang & Jianwen Jiang A molecular simulation study is reported on glucose recovery from aqueous solutions by adsorption in metal-organic framework MIL-101....
His research is focused on the development of polyhedral metal–ligand cages for host–guest studies and chiral separations and on molecular ferro- and piezoelectrics for energy and electronic applications. † These authors contributed equally.View full text...
Considering H2 has no dipole moment, its interactions with the surfaces of cages or channels built by organic ligands are too weak to result in much adsorption at room temperature. Thus, unlike cryo-temperature H2 storage, the density of strong rather than weak interaction sites determines the H2...
Metal-organic frameworks as high-potential adsorbents for liquid-phase separations of olefins, alkylnaphthalenes and dichlorobenzenes. Three metal-organic frameworks (MOFs) with similar pore window diameters, [Cu(3)(BTC)(2)], MIL-47 and MIL-53(Al), are tested for adsorption of olefins, alk....
Metal-organic frameworks can offer pore geometries that are not available in zeolites or other porous media, facilitating distinct types of shape-based molecular separations. Here, we report Fe2(BDP)3 (BDP2– = 1,4-benzenedipyrazolate), a highly stable framework with triangular channels that eff...
Metal–organic frameworks are known to contain defects within their crystalline structures. Successful engineering of these defects can lead to modifications in material properties that can potentially improve the performance of many existing frameworks. Herein, we report the high-throughput computational scr...
Rechargeable organic batteries show great potential as a low-cost, sustainable and mass-producible alternatives to current transition-metal-based cells; however, serious electrode dissolution issues and solubilization of organic redox intermediates (shut