porous organic cagesselective adsorptionself-assemblyImparting mesopores to organic cages of an intrinsic microporous nature to build up hierarchically porous cage soft materials is a grand challenge and will reshape the property and application scope of traditional organic cage molecules. Herein, we ...
Hierarchically porous metal-organic frameworks (H-MOFs) with micro-, meso- and macropores have emerged as a popular class of crystalline porous materials that have attracted extensive interests, and they have been studied in diverse applications, especially in heterogeneous catalysis. The hierarchical ...
Great interests have arisen over the last decade in the development of hierarchically porous materials. The hierarchical structure enables materials to have maximum structural functions owing to enhanced accessibility and mass transport properties, leading to improved performances in various applications. Hier...
This work provides a general method to fast and clean synthesis of porous carbon materials and opens new avenues for the application of metal-organic gel in energy storage. C arbon materials have long been widely used, such as graphite for pencil, carbon blacks for conducting additives, ...
Developing a synthetic methodology for the fabrication of hierarchically porous metal-organic monoliths that feature high surface area, low density and tunable porosity is imperative for mass transfer applications, including bulky molecule capture, heter
(Cu-SAs/NSs), not only because it can tune the pH and contribute to the self-assembly between metal ions and organic ligands, but also because it can decompose and release some gases in-situ during the subsequent pyrolysis, which contributes to the formation of porous structures and Cu-N4 ...
The technique of microtransfer molding was used to prepare materials with two scale or three scale ordered porous material. In this microtransfer molding process a drop of liquid inorganic precursor solution was applied to the patterned surface of a PDMS mold and the excess liquid was removed by...
porous organic cagescrystallinemicroporousmesoporousmacroporousMacroscopic inorganic porous beads are imbibed with a “porous molecular additive” by simple solution processing techniques, resulting in controllable loading and increased surface area. The porous additive consists of soluble organic cage molecules ...
Amali AJ, Sun JK, Xu Q. From assembled metal–organic framework nanoparticles to hierarchically porous carbon for electrochemical energy storage. Chem Commun, 2014, 50: 1519–1522 ArticleCASGoogle Scholar Liang Q, Ye L, Huang ZH,et al.A honeycomb-like porous carbon derived from pomelo peel for...
In general, DME can be produced by methanol dehydration over solid porous acid catalysts, such as most typical catalysts H-ZSM-5 zeolite and γ-Al2O3. Although the DME selectivity is high for methanol dehydration on γ-Al2O3 [20,21], the γ-Al2O3 exhibits much lower activity due to...