Polymerization upon multiple Si–H bond dissociation and subsequent Si–Si bond formation was achieved on Au(111) and Cu(111) surfaces by using two different monomers, each containing two silicon functional groups (CH3SiH2 or SiH3) attached to an aromatic backbone, leading to polymeric disilenes...
A Mechanistic Investigation of the Carbon−Carbon Bond Cleavage of Aryl and Alkyl Cyanides Using a Cationic Rh(III) Silyl Complex Cationic Rh(III) complex [Cp*(PMe3)Rh(SiPh3)(CH2Cl2)]BAr4‘ (1) activates the carbon−carbon bond of aryl and alkyl cyanides (R−CN, where R = Ph,...
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Multiple Si-H Bond Activations by (Bu2PCH2CH2PBu2)-Bu-t-Bu-t and;(Bu2PCH2PBu2)-Bu-t-Bu-t Di(phosphine) Complexes of Rhodium and Iridium... ME Fasulo,E Calimano,JM Buchanan,... - 《Organometallics》 被引量: 2发表: 2013年 Complexes [Fe2(μ-S2ER2)(CO)6] (E = Si, Sn) ...
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Detailed comparisons of the binding and activation of silanes versus H2 on various 16e metal centers suggest a high degree of similarity, but relative ease of OA depends on the electrophilicity of the metal−ligand fragment and other factors such as bond energetics. Increasing the electrophilicity ...
网络有形成共价键结;有形成共价矽碳键结 网络释义
The Si-H bond order decreases from anti to syn caused by a decreasing interaction of the H-ls orbital with the Si-O-pπ type orbitals. 展开 关键词: INDOLE ALKALOID TACAMINE-TYPE METHYL THIOMETHYL ETHER INTRAMOLECULAR CYCLIZATION DOI: 10.1163/156856795X00431 被引量: 14 ...
aBond worksheet for Small SI Certification. Please save this file with the title "Bond worksheet XXXXXXXX20MY.xls" where XXXXXXXX is your company's name 对于小 SI 证书的债券工作表。请以标题“债券工作表 XXXXXXXX20MY.xls”保存此文件哪里 XXXXXXXX 是你的公司的名字[translate]...