reduction reactions under respiring and non-respiring conditions such that the free energy change required for the synthesis of one mole of adenosine triphosphate is equal to that associated with the transfer of two moles of reducing equivalents from one isopotential group to the next isopotential ...
Considering Mn4+ (3d3)-based cations, various layered oxides (A[AyM1鈭抷]O2, where A and M refer to alkali metals and transition metals, respectively) exhibiting oxygen-redox reactions have been investigated extensively to achieve high e... J Lee,S Koo,J Lee,... - 《Journal of Material...
Oxidation–reduction (redox) reactions are central to the existence of life. Reactive species of oxygen, nitrogen and sulfur mediate redox control of a wide range of essential cellular processes. Yet, excessive levels of oxidants are associated with agei
This insight can be used to construct a linear free energy relation for the oxidation potential, which we train on a set of 31 organic redox couples and test on a set of 10 different redox reactions. Better results are obtained when the electronegativity of the oxidized/reduced reagents are ...
operation. These results provide fundamental insights into the mechanisms and kinetics of Li–S redox reactions. Introduction Lithium–sulfur (Li–S) batteries represent one of the most promising candidates of next-generation energy storage technologies, due to their high energy density, natural ...
Redox potential refers to a thermodynamic property that determines the stability of a material towards redox reactions by measuring the voltage difference between a standard hydrogen electrode and the material with its oxidized/reduced species at standard conditions. ...
The formation constants, reduction potentials, and kinetics of some redox and substitution reactions are reported for a series of bis(thiosemicarbazonato) ... DA Winkelmann,Y Bermke,DH Petering - 《Bioinorg Chem》 被引量: 78发表: 1974年 Correlation of cycles in Lava Lake motion and degassin...
Molecular catalysts play a significant role in chemical transformations, utilizing changes in redox states to facilitate reactions. To date molecular electrocatalysts have efficiently produced single-carbon products from CO2 but have struggled to achieve a carbon–carbon coupling step. Conversely, copper cat...
All-solid-state Li-ion batteries promise safer electrochemical energy storage with larger volumetric and gravimetric energy densities. A major concern is the limited electrochemical stability of solid electrolytes and related detrimental electrochemical reactions, especially because of our restricted understanding...