构成氧化还原的成对离子或分子,称为氧化还原对,或氧还对(redoxpair)。氧还电位在标准条件下测定,即得标准氧化还原电位(standard oxidation reduction potentials,E0')。标准氧化还原电位的值越小,提供电子的能力越强。所谓标准条件是指1M反应浓度、25℃、pH7.0和1个大气压,测得的氧还电位用伏特(V)表示。
Increasing Redox Shuttle Oxidation Potentials to Match High Voltage Cathodes in Lithium-Ion BatteriesElectrolyte additives called redox shuttles can protect batteries in series from experiencing overcharge, a condition in which one or more fully charged cells continue to receive applied current, resulting ...
potential的高斯是否可以计算oxidation and reduction potentials？ - 量子化学 (Quantum Chemistry) - 计算...
(2012). "Redox potentials, laccase oxidation, and antilarval activities of substituted phenols." Bioorganic & Medicinal Chemistry 20(5): 1679-1689.Keshar Prasain,Thi D.T. Nguyen,Maureen J. Gorman,Lydia M. Barrigan,Zeyu Peng,Michael R. Kanost,Lateef U. Syed,Jun Li,Kun Yan Zhu,Duy H. ...
The cyclic voltammogram of (TMP)Fe(IV)O, (TMP = 5,10,15,20-tetramesitylporphyrinate), exhibits two quasi-reversible redox waves at E(1/2) = 0.88 and 1.18 V vs SCE in dichloromethane at -60 °C. Absorption spectral measurements for electrochemical oxidation at controlled potential clearly ...
Oxidation-reduction and acid-base reactions are essential for the maintenance of all living organisms. However, redox potential (Eh) has received little attention in agronomy, unlike pH, which is regarded as a master variable. Agronomists are probably depriving themselves of a key factor in crop ...
ChemInform Abstract: THE STANDARD OXIDATION POTENTIALS OF THE (II-III) AND (III-IV) REDOX SYSTEMS OF THE LANTHANIDES AND THE ACTINIDES IN NONAQUEOUS SOLVENTSdoi:10.1002/chin.197803014potentials, cells, elements (inorganic)G. DUYCKAERTSB. GILBERT...
Glutaredoxins belong to the thioredoxin superfamily of structurally similar thiol-disulfide oxidoreductases catalyzing thiol-disulfide exchange reactions via reversible oxidation of two active-site cysteine residues separated by two amino acids (CX1X2C). Standard state redox potential (E degrees ') values ...
(mean absolute deviation of 0.05 V) between the calculated and experimental oxidation potentials; for the azaphenalenes, however, there is an extraordinary discrepancy (mean absolute deviation of 0.60 V), implying that their one-electron oxidation might involve additional processes not considered in ...
The unusually high standard redox potential of the acrylyl-CoA/propionyl-CoA couple is thought to be one of the reasons that in mammals propionyl-CoA is not metabolized by beta-oxidation as in the case of longer acyl-CoAs, but by a methylmalonyl-CoA pathway. The obvious structural difference...