This result is tentatively connected with the generation of local excited states at the catalyst surface.doi:10.1016/j.ijhydene.2010.02.075Francesco DeloguSebastiano GarroniGabriele MulasElsevier LtdInternational Journal of Hydrogen EnergyDelogu F, Garroni S, Mulas G. Hydrogen reactivity toward carbon ...
Reactivity of hydroxyl radicals in aqueous solution. I. Reactions with hydrogen and carbon monoxideDainton, F SHardwick, T JDainton, F.S., Hardwick, T.J., 1957. The reactivity of hydroxyl radicals in aqueous solution. Trans. Faraday Sot. 53, 333-343....
The title compound belongs to the series of methylidine complexes with a 'tetrahedral' Ru3C core; each ruthenium atom links three terminal carbonyl groups and a chain CH2C(CH3)3 is bonded to the apical carbon atom of the core. The presence of the three bridging hydridic atoms is discussed...
Reactivity of a Series of Isostructural Cobalt Pincer Complexes with CO2, CO, and H+The preparation and characterization of a series of isostructural cobalt complexes [Co(t-Bu)2PEPyEP(t-Bu)2(CH3CN)2][BF4]2 (Py = pyridine, E... David,W.,Shaffer,... - 《Inorganic Chemistry》 被引量...
Given that the position-selective introduction of a halide onto an arene is not always straightforward, direct olefination of aryl carbon-hydrogen (C-H) bonds would obviate the inefficiencies associated with generating halide precursors or their equivalents. However, methods for carrying out such a ...
Until very recently, helium had remained the last naturally occurring element that was known not to form stable solid compounds. Here we propose and demonstrate that there is a general driving force for helium to react with ionic compounds that contain a
Synthesis and Reactivity of Ruthenium and Platinum Complexes with Non-Dative Heteroatomic Ligands: Studies of Carbon-Hydrogen Bond Activation. (Under the direction of T. Brent Gunnoe.) Several ruthenium complexes with non-dative heteroatomic ligands were prepared and fully characterized, including TpRu...
Hydride ion transfer from carbon-hydrogen bonds to CS2, COS, and CO2. Synthesis, reactivity, and...Studies the exo hydrogen transfers to CS2 as hydride ion to form HCS2- and (eta 6-C6Me6)Mn(CO)3+. Preparation of cationic precursors to complexes; Kinetic data; Correlation with relative ...
Electrochemical carbon dioxide reduction (CO2R) can provide a sustainable route to produce fuels and chemicals; however, CO2R selectivity is frequently impaired by the competing hydrogen evolution reaction (HER), even for small concentrations of water. Here we tune water solvation and dynamics within...
Bioenergy with carbon capture and storage (BECCS) is looked upon as one of the most promising NETs in spite of some debates over concerns about the timing of CO2 capture and release. The main reasons for this include the renewable nature and widespread availability of biomass, by contrast with...