The predictive capability of the theoretical model is tested against a series of benzylidenemalononitriles and substituted α-nitrostilbenes.Graphicdoi:10.1016/j.tet.2004.06.003Luis R. DomingoPatricia PérezRenato Contreras RamosTetrahedronDomingo LR, Perez P, Contreras R (2004) Reactivity of the carbon...
According to spin density analysis calculated by density functional theory, all Ni(I)–CO species reveal similar spin density at nickel and the carbon atom of CO. X-ray crystallographic data suggest that the corresponding selectivity may be related to the steric influence. For both (acriPNP-Ph...
The reaction of MoCl4(O) with ArNCO (Ar=2,6-iPr2Ph) afforded a series of paramagnetic oxo and imido Mo(V) complexes depending on the nature of the solvent ... dlMF Javier,JW Ziller - 《Journal of Organometallic Chemistry》 被引量: 1发表: 1998年 A Two-Coordinate Cobalt(II) Imido Co...
2.1.6 Carbon source For chars from different sources, several physicochemical properties of char take part in CO2 gasification reactivity. The physicochemical properties of char depend deeply on the utilized carbonaceous feedstock. A vast variety of carbon-based materials including coal, biomass, lignite...
Nitrogen-containing organic carbon (NOC) in atmospheric particles is an important class of brown carbon (BrC). Redox active NOC like aminophenols received little attention in their ability to form BrC. Here we show that iron can catalyze dark oxidative o
(Labcyte, Sunnyvale, CA) to produce a 12-point concentration series with a 2-fold dilution (100–0.05 µM). KDM4E (2 µM) was dispensed across the plate using a Thermo multidrop reagent dispenser (5 µl per well). KDM4E was pre-incubated with the inhibitors for 15 ...
Synthesis, characterization and magnetic studies for a series of compounds having a trinuclear bimetallic Cu-2(II)/Ln(III) system New trinuclear complexes having the general formula [LnCu(2)(Cl)(2)(L)(2)(H2O)(2)]Cl center dot H2O, where L (H2L) = Schiff base ligand and Ln = La...
and acids HX under an ethene atmosphere, are excellent starting materials for the synthesis of a series of new halfsandwich-type ruthenium(II) complexes... T Braun - 《Chemistry》 被引量: 64发表: 2003年 μ-CarbonCarbon Bonds of Dinuclear Manganese Half-Sandwich Complexes as Electron Reservoirs...
10). However, due to the structural features of the carbohydrates, they are prone to undergo the Maillard reaction upon condensation with the primary amine in Trp, which is not a single reaction, but rather a series of mostly undefined reactions leading to undefined products which are largely ...
Thus, the purer the carbon involved in feedstock decomposition, the more likely a higher activation energy becomes. This is due to the assumption about the presence of two parallel gasification reactions. The first reaction with a higher activation energy involves edge carbons, and the second one ...