Inorganic chemistry Transition Metal Catalysts for Hydrogen Storage and Carbon Dioxide Activation YALE UNIVERSITY Nilay Hazari BielinskiElizabeth AnneThis dissertation describes the synthesis of a series of transition metal compounds and their reactivity with hydrogen and carbon dioxide for application in ...
Hydrogen Atom Transfer Rates from Tp-Containing Metal Hydrides to Trityl Radicals The H transfer rate constants for a series of group 6 molybdenum and tungsten pyrazolyl borate complexes are described. The rate constants for these comple... HB Vibbert,H Neugebauer,JR Norton,... - 《Canadian Jour...
The development of catalysts for the hydrogen evolution reaction is pivotal for the hydrogen economy. Thin iron films covered with monolayer graphene exhibit outstanding catalytic activity, surpassing even that of platinum, as demonstrated by a method based on evaluating the noise in the tunnelling curr...
In recent years, fullerene which is a carbon-based material has emerged as a potential candidate for use as noble-metal free electrocatalysts for the hydrogen evolution reaction (HER, 2H + (aq) + 2e ⇄ H2(g)), which is a cathodic half-reaction of water splitting1,2. This...
Hydrogen-abstraction reactivity patterns from A to Y: The valence bond way. Angew. Chem. Int. Ed. 2012, 51, 5556–5578. [Google Scholar] [CrossRef] [PubMed] Stasyuk, O.A.; Sedlak, R.; Guerra, C.F.; Hobza, P. Comparison of the DFT-SAPT and canonical EDA Schemes for the ...
The H2 selectivity follows, in general, a downward shift with increasing temperature, in contrast to CO selectivity. The particular high hydrogen selectivities at lower temperatures (400–500 °C) in the case of Fe-, Co- and Cu-based samples, which exceed the expected theoretical values from ...
Highly organized and adjustable compositions of MOF assisted to emerge as desirable functional platforms for electrocatalytic processes like the hydrogen evolution reaction (HER), oxygen evolution reaction (OER). The structural characteristics and ease of tune-ability put forward engineering strategies of...
At present, photocatalysts have been widely used in hydrogen evolution, degradation of organic pollutants, water decomposition, carbon reduction and microbial disinfectants. Firstly, TMOs are good photocatalyst of semiconductor type. When a light source with energy greater than the semiconductor bandgap ...
Recent Progress in Transition Metal-Catalyzed Addition Reactions of H-P(O) Compounds with Unsaturated Carbon Linkages.- Christian Bruneau: Group 8 metals-cat... Ananikov,P Valentine,Tanaka,... 被引量: 0发表: 0年 Synthesis of Fluorinated Building Blocks by Transition‐Metal‐Mediated Hydrodefluorina...
Visible light induced hydrogen production over thiophenothiazine-based dye sensitized TiO2 photocatalyst in neutral water In this study, we report the design and synthesis of a series of organic sensitizers, namely, (E)-3-(10-butyl-8-(methylthio)-10H-phenothiazin-3-yl)-2-cyanoacrylic acid (UP1...