Qafisheh N,Mukhopadhyay S,Sasson Y.Highly selective Pd-catalyzed reductive coupling of substituted haloarenes with supported phase-transfer catalyst using Zn as the reducing agent. Advanced Synthesis and Catalysis . 2002Gomez S, Peters JA, Maschmeyer T (2002) Adv Synth Catal 344:1037...
Dual Fe/Pd-Catalyzed Reductive Cross-coupling: Constructing gem-Difluoroallylenes with Alkenyl Bromides and Bromodifluoromethanes Guiping Qin, Tao Li, Yuhang Luo, Zefeng Wu, Tiebo Xiao, Yubo Jiang 文章的第一作者是昆明理工大学的硕士研究生李涛。 European Journal of Organic Chemistry DOI: 10.1002...
Herein, we reported a successful cross coupling of aryl sulfonyl chlorides to forge thioether skeleton via Pd catalysis. This transformation proceeded in the presence of Xantphos. Prelimi- nary mechanism studies demonstrated dual roles of Xantphos: (i) a reductant that reduced sulfonyl radical to th...
[5] Muriel Durandetti et al., Ni-catalyzed activation of α-chloroesters: a simple method for the synthesis of α-arylesters and β-hydroxyesters.Tetrahedron2007,63, 1146. [6] Daniel A. Everson et al., Nickel-Catalyzed Reductive Cross-Coupling of Aryl Halides with Alkyl Halides.J. Am. ...
ChemInform Abstract: Pd(0)-Catalyzed Electro-Reductive Hydrocoupling of Aryl Halides with Olefins and Acetylenes.electrochemical reactionsNo abstract is available for this article.doi:10.1002/chin.198614073S.TORIIH.TANAKAK.MORISAKIJohn Wiley & Sons, Ltd...
参考资料[1] https://www.nobelprize.org/[2] Paula Ruiz-Castillo et al., Applications of Palladium-Catalyzed C-N Cross-Coupling Reactions.Chem. Rev.2016,116, 12564.[3] Bryan T. Ingoglia et al., Biaryl monophosphine ligands in palladium-catalyzed C-N coupling:An updated User's guide.Tetr...
Pd-catalyzedC-CCoupling 1.Suzuki-MiyauraCoupling2.SonogashiraCoupling3.HeckReaction4.StilleCoupling5.HiyamaCoupling6.NegishiCoupling7.Kumada-CorriuCoupling8.Cyanation cross-couplingreactions RR'RR'SiR'YR'HYR'Y=N,O,S,P R R'R'MgR'RR'R SnR'X BR'RR'ZnR'RR'RR'RR'...
[3] Bryan T. Ingoglia et al., Biaryl monophosphine ligands in palladium-catalyzed C-N coupling: An updated User's guide. Tetrahedron2019, 75, 4199. [4] Michael S. Driver et al., A Rare, Low-Valent Alkylamido Complex, a Diphenylamido Complex, and Their Reductive Elimination of Amines ...
原文篇名:Pd-Catalyzed C(sp2)–C(sp3) Suzuki Coupling and Synthesis of Lumacaftor Using Designed Monophosphine Ligands 设计并合成了具有 C-P 环的新型单膦配体L1和L2,用于高效的 Pd 催化的 C(sp2)-C(sp3) Suzuki 偶联。以 0.5 mol % Pd2dba3 和 2 mol %L1的芳基卤化物与烷基硼酸偶联,使产品收率高...
Palladium-Catalyzed Tail-to-Tail Reductive Dimerization of Terminal Alkynes to 2,3-Dibranched Butadienes 过度金属催化或介导的炔烃的转化反应已成为合成生物活性化合物、功能材料和天然产物的极其强大的工具。其中,末端炔烃的二聚化作为一种原子经济且简单的合成共轭烯、二烯和二炔的方法,是一直以来关注的重点。在...