then reagent 3 turns the alcohol into a ketone, and finally reagent 4 and 5 performs nucleophilic addition and turns the alcohol into a tetrahedral with CN attached (my steps I drew below). What
PCC, or pyridinium chlorochromate, is a convenient reagent for this transformation as it is easy to handle and readily available. PCC氧化醇是有机化学中常用的方法,可将一级或二级醇分别转化为醛或酮。由于其温和的条件和高效率,这种反应通常优于其他方法。PCC,或者吡啶氯铬酸盐,是这种转化的一个方便试剂...
DABCO-bis-CC: An Efficient Alternative to PCCOxidationchromiumDABCO-bis-CCalcoholketonesaldehydeWe have developed a new chromium based reagent 'DAdoi:10.2174/1570178614666171002150415Saikia, BishwajitLetters in Organic Chemistry
Oxidation of Primary Alcohols to Aldehydes using PCC Description:Treatment of alcohols with PCC leads to formation of the aldehyde. Real-Time Example: Org. Synth. 1967, 47, 25 DOI Link: 10.15227/orgsyn.047.0025 Click to Flip Comments
024781 Overall Score4.5 Generality Reagent Availability Experimental User Friendliness Criteria #4 Criteria #5 General Characteristics The oxidation of alcohols byPCC (Pyridinium Chlorochromate)orPDC (Pyridinium Dichromate)works under mild conditions and can be used for compounds containing unstable functional ...
All chemicals used in this research were purchased from Sinopharm Chemical Reagent Co. Ltd. 2.3. Effect of Cs(I) on Synechococcus PCC7002 Growth The cyanobacteria strain Synechococcus PCC7002 was cultured in medium A supplemented with Cs ions (0–9 g/L) at 32 ◦C while shaking at 150 ...