Outer-sphere complexes of lasalocid and inert metal ammine and amine complexes have also been reported and the crystal structure of one such product, [Co(NH_3)_6]路(Las)_3, has been published. These results prompted a series of studies in which Las~- was used as an ionophore for the ...
The extraction of lanthanide series by Cyanex301, i.e., bis(2,4,4-trimethylpentyl)dithiophosphinic acid (HC301), has been modeled by density functional theory calculation, taking into account the formation of both inner- and outer-sphere complexes. The inner-sphere complex Ln(C301)3 and the...
It was found that, in the complexes with Cu(Salim) a, the CHCIa molecules are arranged out of the plane of the chelate while, with Cu(Salim)aPy, chloroform also forms equatorial outer-sphere complexes. The results are explained by the fact that the planar structure of the chelate is ...
Raman spectroscopic investigation of aqueous FeSO4 in neutral and acidic solutions from 25‡C to 303‡C: inner- and outer-sphere complexes Tremaine, Raman spectroscopic investigation of aqueous FeSO4 in neutral and acidic solutions from 25 oC to 303 oC: Inner- and outer-sphere complexes. ......
The kinetics of outer-sphere electron-transfer reactions between [Co(NH3)5(dmso)]3+(dmso = dimethyl sulphoxide) and a series of [Fe(CN)5L]3– complexes (L = imidazole, ammonia, pyridine, pyrazine, isonicotinamide, or pyrazine-2-carboxamide) have been investigated as a function of the ...
However, these same plots also indicate that in the M(IMP) and M(GMP) complexes formed with Co2+, Ni2+, and Cd2+ an additional outer-sphere coordination to 0-6 is likely. Macrochelation with the alkaline earth ions (formation ... H Sigel,SS Massoud,NA Corfu - 《Journal of the Ameri...
ATR-FTIR characterization of inner-sphere and outer-sphere carbonate surface complexes on hematiteBargar, John RKubicki, James DReitmeyer, RebeccaDavis, J A
ChemInform Abstract: OUTER‐SPHERE AND INNER‐SPHERE INTERACTIONS IN THE FORMATION OF METAL‐ION NITRATE COMPLEXESdoi:10.1002/chin.197913021equilibriaD. F. C. MORRISJ. D. MACCARTHYR. J. NEWTONJohn Wiley & Sons, LtdChemischer Informationsdienst...
The sequential bond dissociation energies (BDEs) of the mono- and bis-benzene complexes with alkali metal cations (Li + , Na + , K + , Rb + , and Cs + ) ar... JC Amicangelo,PB Armentrout - 《Journal of Physical Chemistry A》 被引量: 131发表: 2000年 ...
Values of K a obtained for the three complexes lie in the range (1–2) × 10 3 mol dm 3 which suggest an outer-sphere mechanism. 展开 关键词: bismuth layer crystallization microwave oven ferroelectric properties DOI: 10.1007/s11243-007-0230-6 ...