Inner-sphere and outer-sphere complexes of yttrium(III), lanthanum(III), neodymium(III), terbium(III) and thulium(III) with halide ions in N,N-dimethylform... The formation of chloro, bromo and iodo complexes of yttrium(III), and bromo and iodo complexes of lanthanum(III), neodymium(III...
Outer-sphere complexes of lasalocid and inert metal ammine and amine complexes have also been reported and the crystal structure of one such product, [Co(NH_3)_6]路(Las)_3, has been published. These results prompted a series of studies in which Las~- was used as an ionophore for the ...
ATR-FTIR characterization of inner-sphere and outer-sphere carbonate surface complexes on hematiteBargar, John RKubicki, James DReitmeyer, RebeccaDavis, J A
Solutions of lithium thiocyanate in acetonitrile and in acetonitrile containing tetra-alkylammonium salts have been examined by infrared spectrophotometry. Analysis of the spectra obtained from acetonitrile solutions has yielded formation constants for the inner- and outer-sphere 1:1 complexes with log valu...
Inner-Sphere and Outer-Sphere Water Interactions in Co(II) paraCEST Agents 来自 ACS 喜欢 0 阅读量: 33 作者:SM Abozeid,EM Snyder,TY Tittiris,CM Steuerwald,AY Nazarenko,JR Morrow 摘要: Four macrocyclic complexes of Co(II) that contain amide or alcohol pendents were studied as paraCEST ...
ChemInform Abstract: First‐ and Second‐Sphere Coordination Chemistry of Alkali Metal Crown Ether Complexes Crown ethers exhibit an extremely versatile range of interactions with alkali metal cations in the solid state that goes far beyond simplistic 'size fit' c... JW Steed - 《Cheminform》 被引...
The extraction of lanthanide series by Cyanex301, i.e., bis(2,4,4-trimethylpentyl)dithiophosphinic acid (HC301), has been modeled by density functional theory calculation, taking into account the formation of both inner- and outer-sphere complexes. The inner-sphere complex Ln(C301)3 and the...
No higher associates or anionic complexes are required to interpret the spectroscopic data. In concentrated ZnSO4 the majority of the sulfate is occurring in the outer-sphere. With temperature increase, the amount of inner-sphere complex is increasing (entropically driven reaction). The degree of ...
Inner- and outer-sphere binding of the minor groove site of adenine by alkali metal ions 来自 掌桥科研 喜欢 0 阅读量: 80 作者:AE Gibson,C Price,W Clegg,A Houlton 摘要: Naand Kions exhibit different modes of interaction with the N3 site of the DNA base adenine in a model system.关键...
The underlying mechanism of cation effects on CO2RR remains debated. Herein, we study cation effects by simulating both outer-sphere electron transfer (OS-ET) and inner-sphere electron transfer (IS-ET) pathways during CO2RR via constrained density functi