Outer-sphere complexes of lasalocid and inert metal ammine and amine complexes have also been reported and the crystal structure of one such product, [Co(NH_3)_6]路(Las)_3, has been published. These results prompted a series of studies in which Las~- was used as an ionophore for the ...
Furthermore, the fitted CD values of the various inner-sphere complexes of the mono- and divalent ions can be linked to the microscopic structure of the surface complexes and other data found by spectroscopy as well as molecular dynamics (MD). For the Na + ion, the fitted CD value ...
K. Inner sphere complexes derived from the coordinate interactions of tin(IV) isothio- cyanate moieties with 1-[(4-methylphenylimino)methyl]-2-phenol: Crystal structure of diisothiocyanatodimethylbis {1-[(4-methylphenylimino) methyl]-2-phenol}tin(IV), Me(2)Sn(NCS)(2)center dot[HOC6H...
The formation of chloro, bromo and iodo complexes of yttrium(III), and bromo and iodo complexes of lanthanum(III), neodymium(III), terbium(III) and thulium(III) has been studied by precise titration calorimetry in N,N-dimethylformamide (DMF) at 25 °C. The formation of [YCl]2+, [YCl2...
Analysis of the spectra obtained from acetonitrile solutions has yielded formation constants for the inner- and outer-sphere 1:1 complexes with log values of 3.87 and 3.05, respectively. When added perchlorate is present only the inner-sphere complex is formed with log K= 2.5, but when ...
Inner sphere oxidation of L-ascorbic acid by Ru(III) ion and its complexes in aqueous acidic medium CheminformTaqui Khan, MM, Shukla, RS (1988) Inner sphere oxidation of L-ascorbic acid by Ru(III) ion and its complexes in aqueous acidic medium. ... MMT Khan,RS Shukla - 《Cheminform》...
ChemInform Abstract: OUTER‐SPHERE AND INNER‐SPHERE INTERACTIONS IN THE FORMATION OF METAL‐ION NITRATE COMPLEXESdoi:10.1002/chin.197913021equilibriaD. F. C. MORRISJ. D. MACCARTHYR. J. NEWTONJohn Wiley & Sons, LtdChemischer Informationsdienst...
Raman spectroscopic investigation of aqueous FeSO4 in neutral and acidic solutions from 25‡C to 303‡C: inner- and outer-sphere complexes Tremaine, Raman spectroscopic investigation of aqueous FeSO4 in neutral and acidic solutions from 25 oC to 303 oC: Inner- and outer-sphere complexes. ......
Four macrocyclic complexes of Co(II) that contain amide or alcohol pendents were studied as paraCEST agents and as paramagnetic water shift agents for supramolecular CEST applications. Complexes with bound water or with alcohol pendents produced the largest hyperfine shifted proton resonances of bulk wa...
Two theoretical models, a reorganization model and an activation model, are presented for accurately determining the energy barrier of the type M(H2O) of the transition-metal complexes in the electron-transfer process. Ab initio calculations are carried out at UMP2/6-311G level for several redox...