Ni-catalyzed reductive cross-coupling of alkyl halides with other electrophiles has provided facile protocols to the construction C–C bonds, featuring excellent functional group tolerance and broad substrate scope under mild conditions. While primary and secondary alkyl halides have been extensively ...
ChemInform Abstract: Nickel-Catalyzed Reductive Cross-Coupling of Aryl Halides.polyphenyl derivativesC‐C bond formationThe process takes place under mild conditions to give unsymmetrical biaryls with tolerance for a variety of functional groups.doi:10.1002/chin.201327073...
Transition-metal-catalyzed cross-couplings have been extensively used in the pharmaceutical and agrochemical industries for the construction of diverse C–C bonds. Conventional cross-coupling reactions require reactive electrophilic coupling partners, such as organohalides or sulfonates, which are not environm...
Expedient Synthesis of Chiral α‐Amino Acids through Nickel‐Catalyzed Reductive Cross‐Coupling A novel method for the synthesis of non-natural L- and D-amino acids by a Ni-catalyzed reductive cross-coupling reaction is described. This strategy enable... Lu, Xi,Yi, Jun,Zhang, Zhen-Qi,......
Ni-catalyzed reductive cross-coupling of two unactivated alkyl halides,as well as the coupling of unactivated alkyl halides with allylic carbonates have been successfully developed.The reactions work efficiently for primary and secondary halides,which allow for excellent functional group tolerance,and provid...
Ni-catalyzed reductive cross-coupling of two unactivated alkyl halides,as well as the coupling of unactivated alkyl halides with allylic carbonates have been successfully developed.The reactions work efficiently for primary and secondary... 徐海亮,王书林,赵成龙,... - 全国金属有机化学学术讨论会 被引...
Notably, electrochemical transition metal-catalysis15,16,17,18,19,20, especially Ni-catalysis20, is efficient and powerful in reductive cross couplings. Electro-reductive Ni-catalyzed coupling of aryl halides with organo (pseudo)halides21 and carbonyl-containing compounds22 has emerged as a convenient...
Recent Advances in Nickel-Catalyzed C-Heteroatom Cross-Coupling Reactions under Mild Conditions via Facilitated Reductive Elimination. The formation of C-heteroatom bonds represents an important type of bond-forming reaction in organic synthesis and often provides a fast and efficient acce... C Zhu,H...
Nickel-catalyzed cross-electrophile couplings have emerged as a transformative platform for the construction of carbon–carbon bonds with high levels of enantiocontrol [70], [71]. In this text, metallaphotoredox reductive cross-coupling has garnered significant attention in recent years. In 2020, Ma...
Nickel-catalyzed reductive cross-coupling of aryl bromides with alkyl bromides: Et3N as the terminal reductant Org. Lett., 18 (2016), pp. 4012-4015 View articleGoogle Scholar 44 R.S. Mega, V.K. Duong, A. Noble, V.K. Aggarwal Decarboxylative conjunctive cross-coupling of vinyl boronic ...