Metal-organic frameworks (MOFs) are highly porous hybrid materials consisting of inorganic metal oxide nodes connected by organic linkers. Since their first realization, a wide range of potential applications has been discussed including catalysis1,2,3, gas storage and separation4,5,6, electronic dev...
Metal-organic frameworks (MOFs) are highly porous hybrid materials consisting of inorganic metal oxide nodes connected by organic linkers. Since their first realization, a wide range of potential applications has been discussed including catalysis1,2,3, gas storage and separation4,5,6, electronic dev...
and have been widely investigated on model supports like ultrathinoxide films[9,10,16–25]or a singleepitaxial graphenesheet[26–39]. Another technique that is similar to CVD is the dissociative deposition of anorganometallicprecursor, for example,metal carbonyls. It can be exploited to grow thin...
However, during our experiment, small amount of Rh oxide was observed by XPS. So it is possible the melting point of the Rh–Ir thin film was reduced because of the impurities (metal oxides) in the deposited films43,44. (2) As reported in our previous work, some ligand remained in...
Lithium-ion batteries (LIBs) are witnessing a huge surge in demand for portable electronics, electric vehicles, and grid storage applications. Yet, current LIBs chemistry, pairing lithium transition metal oxide cathodes (LiCoO2, LiMn2O4, LiFePO4, etc.)1with a graphite anode (theoretical specific ca...
The loss in polarization at metal interfaces in the condensed state is a general result for metal-oxide and metal-solution interfaces. However, polarization effects remain significant and comparable to the strength of intermolecular bonds. For example, the relative contributions of electrostatic vs. ...
The loss in polarization at metal interfaces in the condensed state is a general result for metal-oxide and metal-solution interfaces. However, polarization effects remain significant and comparable to the strength of intermolecular bonds. For example, the relative contributions of electrostatic vs. ...
Abstract In this report, we propose a novel framework for toughening brittle oxide glass originated from enhanced ductility by implanting a secondary material comprising different mechanical properties. To do so, copper-metal nanoparticles are implanted into the subsurface layer of commercial soda-lime si...
The atom’s neighboring atoms that are within the allowed bonding distance are examined for chemistry validity. We conducted this process with the help of the cif2lammps library. Python’s multiprocessing library is also used to speed up this process over many structures in parallel. ...
Another system of interest is MOF-7471, consisting of 1D extended metal-oxide pillar nodes connected by dobdc (2,5-dioxido-1,4-benzenedicarboxylate) linkers. They are aligned such that a honeycomb structure of hexagonally shaped 1D-extended pores is formed. This leads to a rhombohedral crystal ...