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H NMR 核磁共振氢谱(1HNMR)➢核磁共振波谱是一种物理方法检测分子中氢原子核（质子）的性质及其周围化学环境的相关 信息（包含分子结构的信息），构成核磁共振结构解析的基础 。核磁共振氢谱可提供的重要信息 ✓化学位移——电子云密度 ✓耦合常数及峰的裂分情况——邻近质子情况 ✓峰面积——质子个数 运用...
系统标签: gstab revealing pure shift nmr robust “Pureshift”1HNMR,arobustmethodforrevealingheteronuclearcouplingsincomplexspectra.JuanA.Aguilar,aGarethA.MorrisbandAlanM.Kenwright*aSupplementaryInformationIndex:Pulsesequence:PSB1D.cPhase-cycletable:PSB1D.tblAssemblermacro:pureshiftSimulationsElectronicSupplementar...
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H-C(8) couples to C(7), C(9), and C(10), and H-C(10) couples to C(7), C(8), C(9) in addition Table 1 1H- and 13C-NMR shifts of atrop-abyssomicin C, abyssomicins B, G, and Ha atrop-abyssomicin C (4) abyssomicin B (2) No. d (1H) d (13C) d (1H) ...
We found that the C11 halogen modulated affinity across all three opioid receptors: the 11-F compound 22 exhibited greater affinity compared to the parent 7OH, but this gain in binding was progressively lost as the halogen became larger (compounds 23 and 24, Table 1). This effect was most ...
Table 1.1 gives the spin quantum numbers and allowed nuclear spin states for selected isotopes of elements common to organic compounds Element Nuclear spin quantum number ( I ) Number of spin states 1 H 2 H 12 C 13 C 14 N 16 O 31 P 32 S 1/2 2 1 3 0 1 1/2 2 1 3 0 1 1/...
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