cAMP-regulated phosphoprotein-19HA-detection, intrinsically disordered proteinNMR spectroscopyProtein Phosphatase 2A, PP2A, the principal Serine/threonine phosphatase, has major roles in broad range of signaling pathways that include regulation of cell cycle, cell proliferation and neuronal signaling. The ...
若数据不同则主要依据较新文献提供的校正过的数据或在较稀 的惰性溶剂中测定的数据. 表1 计算苯甲醛亚胺 犘犺犆犎=犖 犡亚胺基氮15犖犖犕犚化学位移时采用的取代基参数 15 Table1TheSubstituentChemicalShiftsforcalculatinNNMRchemicalshift g ofhenliminesPhCH=NX py SubstituentChemicalShiftsofX SubstituentX () ...
NMR 化学位移误差为 Δδ±5 ,是可以允许的 . 公式( 1 )中约有 94.7% 的 15 NNMR 化学 位移计算值的计算误差在 δ5.0 的范围内(相对误差小于 0.5% ),这说明公式( 1 )基本能 够准确地计算脂肪胺类化合物氨基氮 15 NNMR 的化学位移 . 表 2 计算脂肪胺氨基氮 15 犖犖犕犚 化学位移时采用的取代基...
Biomolecular NMR Assignments (2023) 17:257–263 https://doi.org/10.1007/s12104-023-10151-5 ARTICLE 1H, 13C, and 15N NMR chemical shift assignment of LytM N‑terminal domain (residues 26–184) Ilona Pitkänen1 · Helena Tossavainen1 · Perttu Permi1,2,3 ...
Nitranions and Their Precursors: Charge Density Rearrangements and 15Nitrogen NMR Chemical Shift Changes. J. Am. Chem. Soc. 1992, 114, 8634- 8644. (b) Buttingsrud, B.; Alsberg, B. K.; Astrand, P.-O. An Investigation of Descriptors Based on the Critical Points in the Electron Density...
The15NnitrideNMR spectroscopic data for1*prompted us to computationally model its NMR properties in detail. We used coordinates from geometry optimisation (see Supplementary Table1) at the BP86 level39, noting the computed U ≡ N bond length of 1.7795 Å compares well to the crystallog...
The present work is aimed at accomplishing the following goals: (1) improving on the optimization 1H-15N DCs, (2) increasing the reliability of NMR experiment simulations to predict experimental results, and (3) generalizing this method to computer optimizations of other NMR experiments, namely for...
Table 1. Signal-to-noise comparison for the 15N R1 and R2 (R1ρ) NMR relaxation experiments recorded on 1H 15N Syb-2, using the sensitivity-enhanced HSQC-detection or for comparison using the TROSY-detection scheme. (A) The SNR is calculated by taking the average of the three most intense...
Biomolecular NMR Assignments (2021) 15:165–171 https://doi.org/10.1007/s12104-020-10000-9 ARTICLE 1H,13C and 15N chemical shift assignments of the SUD domains of SARS‑CoV‑2 non‑structural protein 3c: "The SUD‑M and SUD‑C domains" Angelo Gallo1 · Ai...
2-dimensional NMR (1).13 ISHere we report on a C and N NMR study on FMN bound to the apoflavodoxinfrom Desulfovibrio vulgaris.Results and Discussion13 15The C and N chemical shifts of FMN free and bound to D.vulgaris flavo-13doxin are summarized in Table 1. Figure 1 shows the ...