1 H NMR study of the solvolysis of the paramagnetic tetrachloro-bis(imidazole)ruthenium(III) anion in water, methanol, and dimethyl sulfoxide The 1H NMR signals of the Ru(III) species present in solution are considerably broadened and shifted by paramagnetism, but they can be used to follow ch...
The new complexes have been characterized by IR, UV–Vis and H NMR spectroscopic methods. In addition, the structure of one of the complexes, [RuCl(DMSO)(tcah)]·HO (tcah = thiophene-2-carboxylic acid hydrazide), has been determined by single crystal X-ray diffraction. All the studies ...
marginal peak could not be found in aqueous solution containing DMSO.In addition,with increasing amount of protein,T m (II)shifted toward lower temperature,and ΔH m (II)decreased along with the temperature gap between two transitions lengthened.The results were considered to be due to the ...
Holz M, Heil SR, Sacco A (2000) Temperature-dependent self-diffusion coefficients of water and six selected molecular liquids for calibration in accurate 1h nmr pfg measurements. Phys Chem Chem Phys 2(20):4740–4742. https://doi.org/10.1039/B005319H Article CAS Google Scholar Horn HW, Sw...
The distribution of step sizes is broad and displays a peak at 60 nm (180 bp) as well as a long tail. This distribution is essentia... TR Strick,T Kawaguchi,T Hirano - 《Current Biology》 被引量: 197发表: 2004年 Exploring conformational space with a simple lattice model for protein ...
The structures of the polymers 3 were supported by H-1 NMR, B-11 NMR, and IR spectra. The obtained polymers were soluble in common organic solvents such as tetrahydrofuran, chloroform, and benzene. The peak due to the pi-pi* transition of 3a was observed at 415 nm, which was ...
We did not detect any peak in our EPR measurements on Na-1, thus supporting the conclusion that Na-1 is diamagnetic in its ground state.doi:10.1007/s10876-007-0180-3Li-Hua BiSib Sankar MalNadeen H. NsouliMichael H. DickmanUlrich Kortz...
H-1 NMR2D NMRCYTOCHROME C COMPLEXESLow-energy collisions of ionized acetone- d 6 , DMSO- d 6 and pyridine- d 5 with alkanethiolate self-assembled monolayer (SAM) surfaces prepared on gold were investigated. These experiments can be used to monitor routinely the condition of the surfaces and ...