同时活泼氢会与 DMSO-d6 的氧原子形成氢键，减缓交换过程。DMSO为溶剂测定核磁共振氢谱，活泼氢常常表现...
Proton nmr parameters are reported for DMSO-d6 solutions of two receptor-selective substance P analogues: Ac[Arg6, Pro9]SP6-11, which is selective for the NK-1 (SP-P) receptor and [pGlu6, N-MePhe8]SP6-11, which selectively activates the NK-3 (SP-N) receptor. Full peak assignments...
Proton nmr parameters are reported for DMSO-d6 solutions of two receptor-selective substance P analogues: Ac[Arg6, Pro9]SP6-11, which is selective for the NK-1 (SP-P) receptor and [pGlu6, N-MePhe8]SP6-11, which selectively activates the NK-3 (SP-N) receptor. Full peak assignments...
Proton nmr parameters are reported for DMSO-d 6 solutions of two receptor-selective substance P analogues: Ac[Arg 6 , Pro 9 ]SP 6-11 , which is selective for the NK-1 (SP-P) receptor and [pGlu 6 , N-MePhe 8 ]SP 6-11 , which selectively activates the NK-3 (SP-N) receptor....
H-1 NMR2D NMRCYTOCHROME C COMPLEXESLow-energy collisions of ionized acetone- d 6 , DMSO- d 6 and pyridine- d 5 with alkanethiolate self-assembled monolayer (SAM) surfaces prepared on gold were investigated. These experiments can be used to monitor routinely the condition of the surfaces and ...
Here, we have attempted to decipher the early events in the folding of Dynein Light Chain protein (DLC8), starting from DMSO-d6 denatured state. Multinuclear NMR experiments were used to obtain the full spectral assignment. The HSQC spectrum shows the presence of two sets of peaks for the ...
Experiment (b, yellow-powder): 31P{1H} NMR(DMSO-d6): δ −8.57 (s, mPTA) (1) (ratio 1a:1 = 0:100%). 3.5. Reaction of [RuClCp(mPTA)(PPh3)](OSO2CF3) (1a) with mPTA(OSO2CF3) Complex 1a (100 mg, 0.13 mmol) was added to mPTA(OSO2CF3) (49 mg, 0.15 mmol) ...