该工作解决了目前环加成反应中多相催化剂活性低导致的依赖高纯CO2和高温/高压问题。以上研究成果以“Unveiling the incorporation of dual hydrogen-bond-donating squaramide moieties into covalent triazine frameworks for promoting low-concentra...
Bi2O3catalyst with Bi-O bond crystal structure has more active sites, which shows better CO2catalytic performance than pure Bi catalysts in many catalytic reactions. How to strengthen the Bi-O bond in Bi2O3to obtain higher sele...
将聚醌修饰到Cu气体扩散电极内,并进行CO2/纯水膜电解器的装配测试,在3.5V低电解槽压下C2H4产生的净电流密度达到325mA/cm2。这一研究发表在国际知名期刊《ACS Energy Letters》上,题为“Polyquinone Modification Promotes CO2 Activation and Conversion to C2+ Products over Copper Electrode”。该研究为高效CO2还原...
activated CO2 species under light easily couple to form oxalate with the barrier of 0.19 eV, and further reduced to C2H6 with a low activation energy of 1.09 eV. 可见光照下CO2分子活化机理
Comparing to breakdown voltage predictions using methods based on bond energy, Paschen's law and high voltage tests. Breakdown voltage deviations using bond energy were better than Paschen's law. The dichlorotrifluoroethane gas economy has a price of 5.18 times cheaper than hexafluoride sulfur gas....
Prediction of binding bond energy between phosphorous-based ionic liquids and CO2. Assessment of the CO2–anion interactions (2012) Prediction of binding bond energy between phosphorous-based ionic liquids and CO2: Assessment of the CO2-anion interactions. Ionics, 18:143-150... A Indarto,J Palgun...
关键词:二氧化碳;环状碳酸酯;功能化离子液体;硅基介孔材料;多相催化Abstract-III-AbstractCO2isoneofthemaingreenhouseeffectgases,andhasbeenattractingmuchattentionasanabundant,inexpensive,nontoxic,andrenewableC1resource.Forbenefittingtheeco-environmentanddevelopingnewrenewableenergy,therealizationofanefficientcatalyticprocess...
Identification of possible pathways for C–C bond formation during electrochemical reduction of CO2: new theoretical insights from an improved electrochemical model. J. Phys. Chem. Lett. 7, 1471–1477 (2016). Article CAS PubMed Google Scholar Montoya, J. H., Peterson, A. A. & Nørskov,...
ACS Energy Lett. 6, 2952–2959 (2021). Article Google Scholar Oßkopp, M. et al. Producing formic acid at low pH values by electrochemical CO2 reduction. J. CO2 Util. 56, 101823 (2022). Li, J. & Kornienko, N. Electrocatalytic carbon dioxide reduction in acid. Chem. Catal. 2...
研究组由Prof. Alan M. Bond (澳洲科学院院士)及张杰副教授 (ARC Future Fellow)联合领导。研究组在现代电化学理论及仪器方面基础深厚,与众多世界范围内知名电化学专家有合作关系。课题组近年来在CO2电催化还原方面开展了多项原创性研究,如10.1039/C5EE02879E,10.1002/ange.201710038,10.1002/anie.201608279等。