We have determined the bond dissociation energy of O-2 by measuring fully state-to-state resolved threshold fragment yield spectra in the XUV energy region, O-2(X-3 Sigma(-)(g),N",J") -> O(P-3(J))+O(S-3(1)o)/O(S-5(2)o). Our results have yielded a bond dissociation ...
翻译 bond dissociation energy 英[bɔnd diˌsəuʃiˈeiʃən ˈenədʒi] 美[bɑnd dɪˌsosiˈeʃən ˈɛnədʒi] 释义 键裂解能 释义
At the molecular level, sensitivity is closely related to the bond dissociation energy (BDE) of trigger linkages like C/N/O-NO2 in the widely used nitro compounds. Herein, the BDE of C-NO2 in a series of designed five- and six-membered N-heteroaromatic derivatives, including pyrrole, ...
Thus, in order to break the bond, energy must be provided to the molecule (bond-dissociation energy). As a matter of fact, the amount of energy required to break the bond is the same as that released upon formation of the bond. D is expressed in either kJ/mol or kcal/mol2....
Energy flow and C-H-methyl and C-H-ring bond dissociations in vibrationally excited toluene in the collision with N-2 and O-2 have been studied by use of classical trajectory procedures. The energy lost by the vibrationally excited toluene upon collision is not large and it increases slowly...
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(BDE) •Theenergyabsorbedorreleasedinanyreaction,symbolized by H 0 ,iscalledtheenthalpychangeorheatofreaction. •BDEisthe H 0 foraspecifickindofreaction—thehomolysis ofacovalentbondtoformtworadicals. 12 BondDissociationEnergy •Becausebondbreakingrequiresenergy,bonddissociation energiesarealwayspositive...
It is shown that the very large variations in the C H and C C homolytic bond-dissociation energies for a large variety of organic compounds can be rationalized in terms of the stabilization energies of these species and their corresponding radical(s). In most cases, these stabilization energies...