The bond dissociation energy of Co has been measured by the onset of predissociation in a dense electronic spectrum by the detection of the fragment Co ion. The value obtained, D (Co ) = 2.765卤0.001 eV, compares well to the previously accepted value of 2.75卤0.10 eV, obtained using ...
Before 2001, there was not a theoretical attempt to estimate the Co CR bond dissociation energy (BDE) in models of coenzyme B12. Two recent papers addressed this issue and provided theoretical estimation of BDEs for Me-B12 and Ado-B12 [29••,31]. For Me-B12, the experimental ...
来源期刊 Journal of the American Chemical Society 1987/12/01 研究点推荐 actinide-carbon -bond hydrogenolysis actinide hydrocarbyl ligand hydrogenolysis Metal, bond energy, and ancillary ligand effects 引用走势 2013 被引量:3 站内活动 0
The trend of decreasing bond energy with added N2 ligands is a result of weaker orbital interactions. The exception is Cr(N2)6, which is predicted to be more stable than the CO containing complexes. This increase in stability is ascribed to the absence of a CO trans effect. In contrast, ...
The bond dissociation energy of CO (1072 kJ/mol) is the strongest chemical bond, stronger than the octet rule, four of Nth2etrsihpalreebdoenledct(r9o4n2s kiJn/mColc)o4.mTehefroomxidOatiaonndsotantelyotfwCo in CO is +2. According to the come from C, so one bonding orbital ...
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Energy decomposition analysis of the metal-imine bond in [(CO)4M–SB] (M = Cr, Mo, W; SB: RHCN–CH2CH2–NCHR) The electronic and molecular structures of the metal-Schiff base complexes [(CO)4M–SB] (M: Cr, Mo, W; SB: RHCN–CH2CH2–NCHR, R = C6H5, C6F5, Ortho-... Me...
The reactions of ethanol and 1-propanol on a 1.3 monolayer Co overlayer was investigated in an effort to understand the reactivity of Co thin films deposit... DA Chen,CM Friend - 《Langmuir》 被引量: 32发表: 1998年 Intramolecular energy transfer in highly vibrationally excited methanol. IV. ...
The Fund does not currently commit to invest in fossil gas and/or nuclear energy related activities that comply with the EU Taxonomy, however, these investments may form part of the portfolio. BlackRock has developed a highly automated compliance process to help ensure that the Fund is managed ...
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