ChemInform Abstract: Gas Phase Basicity and Acidity of Amines (63 Literaturangaben)organic chemistry, reviewResults of laboratory measurements are presented for gas-phase reactions of ground-state atomic silicon ions in the absence and presence of naphthalene, the simplest polycyclic aromatic hydrocarbon ...
The p K B showed that IIIa is a substantially weaker base than analogous carbon amines. The results are accomodated by d π p π bonding in the ground state, although an additional factor, the "adjacent charge rule" may also be involved.doi:10.1002/chin.197426129...
However, the p K ams values at 70% v/v CH3CN become nearly equal or slightly larger (by ≤0.7 p K units) than the corresponding p K ams at 2% v/v CH3CN for all neutral and charged amines. The values of p K ams for phenol increase from 10.17 to 13.38 with the increase in the...
The use of global and local molecular- parameters for the analysis of the gas-phase basicity of amines. J. Am. Chem. Soc. 108 (19), 5708-5711.Yang, W.; Mortier, W. J. The use of global and local molecular parameters for the analysis of the gas-phase basicity of amines. J. Am....
Comparison of acidity function and linear free energy basicity constants of amides, phenylureas, and nitroanilineselectrolytes, electrolytic conductivity, acid/base properties (organicprotonation, deprotonationamines (benzene compoundscarboxylic amides (benzene compounds...
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Ionization energies of some amines and enamines and an estimation of their relative basicity in gaseous phaseelectron spectra, ESCA (organic substancespyrrole derivativespyridine derivativesNo abstract is available for this article.doi:10.1039/f29757101572Francesco Paolo Colonna...
ChemInform Abstract: STUDIES ON THE ACIDITY AND BASICITY OF ALKOXYSILYLAMINESorgano‐silicon compounds, acyclic O,N,S derivativesNo abstract is available for this article.doi:10.1002/chin.197912276J. PIKIESW. WOJNOWSKIE. POPOWSKIH. KELLING
amines (benzene compounds)No abstract is available for this article.doi:10.1002/chin.197549174RONALD KLUGERC.‐H. LAMJohn Wiley & Sons, LtdCheminformKluger, R.; Lam, C. H. Effects of leaving group basicity on the hydrolysis of aryl-substituted maleanilinic acids. J. Am. Chem. Soc. 1975,...
The effect of the basicity of methyl-amines on hydrogen bonding (HB) with HCOOH is examined in both gas and solution phases. In the gas phase, the strength of HB may be related to the proton affinity (PA) difference between the carboxylate anion and the methyl-amine, ΔPA=PA(HCOO)PA(...