Basicity of nucleophilic carbenes in aqueous and nonaqueous solvents-theoretical predictions. Correlation of Relative Rates and Equilibria with a Double Basicity Scale The use of global and local molecular parameters for the analysis of the gas-phase basicity of amines ...
Today we’ll look at a simple periodic basicity trend across the periodic table and extrapolate from it some general principles for acid base reactions in organic chemistry. “Basicity” Is Just Another Word For “Stability Of A Lone Pair Of Electrons” Which Of These Acid-Base Reactions Would ...
Table 3. Gas-phase basicities of oligomers of glycine, alanine, and valine. Values are referenced by using the LLL basicity scale [6] GB Ikcal/rnol) n (GIY)n (Ala)n (Val)n 1 203.1 ± 0.6 204.9 ± 1.3 207.3 ± 0.7 2 208.5 ± 0.6 210.6 ± 0.5 212.6 ± 0.8 3 209.6 ± 0.6 ...