5-Hydroxymethyl-2-furancarboxylic acidHeterogeneous base catalystMicrowave-assisted catalysisAEROBIC OXIDATION25-FURANDICARBOXYLIC ACIDLIGNOCELLULOSIC BIOMASSNANOPARTICLESCHEMICALSThis work revealed 5-hydroxymethylfurfural (HMF) oxidation towards 5-hydroxymethyl-2-furancarboxylic acid (HMFCA) employed Ag2O supported on...
To decrease the 5-hydroxymethyl-2-furancarboxylic acid (HMFCA) bioconversion cost, an optimized strategy for HMFCA production from agriculture wastes were established in this study. Corncob residue (CCR) and soybean dreg were hydrolyzed by Pseudomonas aeruginosa PC-1 as substitutes for the traditional...
Sun, K.J. Deng, Aerobic oxidation of biomass derived 5-hydroxymethylfurfural into 5-hydroxymethyl-2-furancarboxylic acid (HMFCA) catalyzed by montmorillonite... Wang, Yimei,Liu, Bing,Huang, Kecheng,... - 《Ind. Eng:chem》 被引量: 45发表: 2016年 ...
In this study, selective biooxidation of HMF to 5-hydroxymethyl-2-furancarboxylic acid (HMFCA) by Pseudomonas putida KT2440 with superior titer, yield, and productivity was reported. The biocatalytic performances of P. putida KT2440 were optimized separately. Under optimal conditions, 100% yield ...
An efficient method for the catalytic aerobic oxidation of 5-hydroxymethylfurfural (HMF) to 5-hydroxymethyl-2-furancarboxylic acid (HMFCA) was developed using size-controlled Ag nanoparticles (NPs) in an aqueous solution. A series of AgNPs catalysts stabilized by poly(vinylpyrrolidone) (PVP) ...
Sun, K.J. Deng, Aerobic oxidation of biomass derived 5-hydroxymethylfurfural into 5-hydroxymethyl-2-furancarboxylic acid (HMFCA) catalyzed by montmorillonite K-10 clay immobilized molybdenum acetylacetonate complex, Green Chem. 16 (2014) 2558-2565....
5-Hydroxymethyl-2-furancarboxylic acid (HMFCA, 57-90%) was formed only at low concentration of 5-HMF (< 0.03 M) or in presence of external bases. The conversion of 5-HMF ranged from a few percent to 99%, according to the reaction conditions. The oxidation was performed in water, with...
The selective oxidation of 5-hydroxymethylfurfural (HMF) to 5-hydroxymethyl-2-furancarboxylic acid (HMFCA) has been investigated on Co-based MOF catalysts. ZIF-67 (ZIF, Zeolitic Imidazolate Framework), Co-BTC and Co-BTC-2mim were solvothermally synthesized by the association of cobalt with 2-me...
FCA and 5-hydroxymethyl-2-furancarboxylic acid (HMFCA) were obtained with the yields of 95鈥 98%. FCA of up to 147 mM was produced by a fed-batch strategy, in a quantitative yield. In addition, most aromatic aldehydes tested were transformed into the target carboxylic acids by this ...
The catalysts were used for the aerobic oxidaiton of 5-hydroxymethylfurfural(HMF) into 2,5-furandicarboxylic acid (FDCA) in an alkaline aqueous solution. The monometallic Pd or Au catalyst could not oxidize the intermediate product-5-hydroxymethyl-2-furanic acid (HMFCA), while bimetallic Pd-Au...