Of the whole-cell biocatalysts constructed, Escherichia coli expressing a vanillin dehydrogenase (E. coli_CtVDH1) proved to be the best for the oxidation of 5-hydroxymethylfurfural (HMF). 5-Hydroxymethyl-2-fura
别名 5-(羟甲基)呋喃-2-甲酸 | Sumiki酸 英文别名 CHEBI:89118 | ethyl 2-aminopropanoate;hydrochloride | 5-(Hydroxymethyl)-2-furoic acid | AS-18462 | Nepsilon-Cbz-D-lysine | DTXSID5033098 | AM20100567 | Tox21_201082 | 1,2-dioctadecanoyl-rac-glycerol | 5-hydroxymethylfurancarboxylic acid ...
To decrease the 5-hydroxymethyl-2-furancarboxylic acid (HMFCA) bioconversion cost, an optimized strategy for HMFCA production from agriculture wastes were established in this study. Corncob residue (CCR) and soybean dreg were hydrolyzed by Pseudomonas aeruginosa PC-1 as substitutes for the traditional...
5-Hydroxymethyl-2-furanoic acid CAS号6338-41-6 分子式C6H6O4 分子量142.11 中文别名5-羟甲基-2-呋喃甲酸;5 - (羟甲基)-2 - 呋喃甲酸标准品;5-羟甲基-2-糠酸;5-(羟基甲基)-2-糠酸;5-羟甲基呋喃甲酸 英文别名5-Hydroxymethyl-2-furancarboxylic acid;5-(hydroxymethyl)furan-2-carboxylic acid;5-Hydroxy...
5-hydroxymethyl-2-furancarboxylic acid (HMFCA), 5-formyl-2-furancarboxylic acid (FFCA), 2,5-furandicarboxylic acid (FDCA), and HMF esters can be prepared from HMF. These bio-based chemicals can be used in pharmaceuticals, furan-based polyesters, spices, disesel additives, etc. However, ...
例如,hmf经选择性氧化可分别转化为2,5-二甲酰基呋喃(dff)、5-羟甲基糠酸(5-hydroxymethyl-2-furancarboxylicacid,hmfca)、5-甲酰基糠酸(ffca)及2,5-呋喃二甲酸(fdca),结构如图1所示。这些氧化衍生物都是重要合成砌块,在能源、医药、高分子等领域具有重要的应用价值(greenchem.,2015,17,3718)。例如,hmfca既...
5-hydroxymethyl-2-furancarboxylic acid (HMFCA), 5-formyl-2-furancarboxylic acid, and 2,5-furandicarboxylic acid (FDCA) [8]. Among them, HMFCA, formed by selective oxidation of the aldehyde group on HMF, is a less known oxidative product, which has potential applications in fields of material...
in Escherichia coli for cascade catalytic oxidation of 5-hydroxymethylfurfural (HMF) to FDCA under sacrificial substrate-free conditions. HMF was rapidly transformed to 5-hydroxymethyl-2-furancarboxylic acid (HMFCA) by VDH1, followed by subsequent oxidation to 5-formyl-2-furancarboxylic acid (FFCA) ...
Chitosan-derived, porous nitrogen-enriched carbonaceous carbon nitride catalyst (PCNx) has been synthesized from marine waste and its use demonstrated in a metal-free heterogeneous selective oxidation of 5-hydroxymethyl-furfural (HMF) to 2,5-furandicarboxylic acid (FDCA) using aerial oxygen under mild...
The selective oxidation of 5-hydroxymethylfurfural (HMF) to 5-hydroxymethyl-2-furancarboxylic acid (HMFCA) has been investigated on Co-based MOF catalysts. ZIF-67 (ZIF, Zeolitic Imidazolate Framework), Co-BTC and Co-BTC-2mim were solvothermally synthesized by the association of cobalt with 2-me...