2-Methylimidazole palladium(II) complexesThe preparation of two new tetracoordinated complexes of palladium(II) with 2-methylimidazole, 2-MeIm, and chloride as ligands is described.doi:10.1007/BF00619475M José CamazónAmparo Alvarez-ValdésJosé R. MasaguerM. Carmen Navarro-Ranninger...
The syntheses, FT-IR and UV–Vis spectra, thermal analyses and crystal structures of Mn(II) and Cu(II) orotate coordination polymers with 2-methylimidazole (2-meim) and N,N,N′ ,N′-tetramethylethylenediamine (tmen) ligands are described. The orotate ligand acts as a bridging ligand with...
Besides, when this composite was explored as a heterogeneous catalyst for catalytic conversion of carbon dioxide with epichlorohydrin (ECH) as probe, an obvious enhancement in catalytic activity was obtained compared with the fresh Co-BTC, suggesting that 2MeIm ligands within the ...
It was found that except for the crystal faces (0 1 1) and (1 0 2) corresponding to ZIF-67 and Co-BTC, a new crystal phase appeared at 12.22o for the modified Co-BTC, which may be attributed to the coordination between 2MeIm and unsaturated Co ions of Co-BTC. Interestingly, a ...
2-Methylimidazole (2-MeIm) reacts with RuCl[sub 3] in aqueous acidic ethanolic medium to give (2-MeImH)[sub 2] [RuCl[sub 5] (2-MeIm)] (1) and (2-MeImH)[RuCl[sub 4] (2-MeIm)[sub 2] ] (2) (2-MeImH = protonated 2-methylimidazole), the ratio depending on reaction ...
Two new mixed-ligand coordination polymers, {[Co(μ1,3-sq)(H2O)2(2-Meim)2]·2(2-Meim)}n (1) and [Cd(μ1,3-sq)(H2O)2(4(5)-Meim)2]n (2), (sq = squarate, 2-Meim = 2-methylimidazole, 4(5)-Meim = 5-methylimidazole) have been synthesized and structurally...
Spectral changes in the increased amount of 2-MeImH; Resonance Raman spactral changes; Photoreduction of iron porphyrin.UnoTadayukiHatanoKeiichiroJournal of the American Chemical Society
electrocatalytic propertyoxygen reductionA novel mixed-ligand complex [CuL(2-MeIm)(H2O)] was synthesized and characterized by elemental analysis, IR, and single-crystal X-ray diffraction. In the structure, Cu (II) was five-coordinated by three O atoms and two N atoms. L acted as a ...
electrocatalytic propertyoxygen reductionA novel mixed-ligand complex [CuL(2-MeIm)(H2O)] was synthesized and characterized by elemental analysis, IR, and single-crystal X-ray diffraction. In the structure, Cu (II) was five-coordinated by three O atoms and two N atoms. L acted as a ...
Crystal structure2-D sheetCVGenotoxic studiesThe title complexes were obtained from the reaction of VOSO4 with imidazole or 2-methyl imidazole in presence of adipic acid/iminodiacetic acid. X-ray crystallographic investigations on [H2V10O28](2-MeImzH)4 (2) revealed a strong interaction between ...