2-Methylimidazole palladium(II) complexesThe preparation of two new tetracoordinated complexes of palladium(II) with 2-methylimidazole, 2-MeIm, and chloride as ligands is described.doi:10.1007/BF00619475M José CamazónAmparo Alvarez-ValdésJosé R. MasaguerM. Carmen Navarro-Ranninger...
The average lengths of the M–N(Pc) and M–N(MeIm) bonds in 1 are 1.956(3) and 2.055(2) Å, and they are elongated up to 1.987(1) and 2.161(1) Å, respectively, in 2. The formation of the 19π-electron system of Pc·3– results in partial disruption of the aromaticity ...
The syntheses, FT-IR and UV–Vis spectra, thermal analyses and crystal structures of Mn(II) and Cu(II) orotate coordination polymers with 2-methylimidazole (2-meim) and N,N,N′ ,N′-tetramethylethylenediamine (tmen) ligands are described. The orotate ligand acts as a bridging ligand with...
The synthesis and detailed study of the new mononuclear spin crossover complex [Fe(II)H2L(2-Me)](ClO4)2 (where H2L(2-Me) = bis[((2-methylimidazol-4-yl)meth... N Bréfuel,S Imatomi,H Torigoe,... - 《Inorganic Chemistry》 被引量: 55发表: 2006年 Spin-Crossover in the Complex...
The 4-MeIm ligands are N-coordinated in cis positions. The complex crystallizes in the triclinic space group p1 with unit cell parameters a = 9.204(5), b = 9.498(5), c = 13.095(5) , α = 90.395(5), β = 101.687(5), γ = 112.291(5)° and Z = 2. Hydrogen bondings and C-...
2-methylimidazole imidazoleCore-shell structureIn this work, Cu2O/Cu(2-MeIm)2 core-shell structure was designed and used as an anode for potassium-ion batteries. The Cu2O core not only ensured a high energy density through surface redox reactions, but also served as a copper-ion reservoir to...
zeolite-Y encapsulated metal complexeshydrogen peroxide decompositionoxidation of phenoloxidation of benzyl alcoholCopper(II), ruthenium(III) and zinc(II) complexes of 2-methylimidazole (2-MeImzlH) encapsulated in the supercages of zeolite-Y have been synthesized and characterized by various ...
2-Methylimidazole (2-MeIm) reacts with RuCl[sub 3] in aqueous acidic ethanolic medium to give (2-MeImH)[sub 2] [RuCl[sub 5] (2-MeIm)] (1) and (2-MeImH)[RuCl[sub 4] (2-MeIm)[sub 2] ] (2) (2-MeImH = protonated 2-methylimidazole), the ratio depending on reaction ...
Reports the formation of the Fe(OEP)(OME) complex by titrating Fe(OEP)(Cl) with 2-MeImH in the presence of a trace amount of methanol. Spectral changes in the increased amount of 2-MeImH; Resonance Raman spactral changes; Photoreduction of iron porphyrin.Uno...
[(CH3)(2)NH2][Co-3(BTC)(HCOO)(4)(H2O)]H2O (Co-BTC) was synthesized under solvothermal conditions, further used as the precursor for the synthesis of 2-methylimidazole modified Co-BTC (2MeIm@Co-BTC-x). The characteristics of 2MeIm@Co-BTC-x were systematically characterized by various...