2-Methylimidazole palladium(II) complexesThe preparation of two new tetracoordinated complexes of palladium(II) with 2-methylimidazole, 2-MeIm, and chloride as ligands is described.doi:10.1007/BF00619475M José CamazónAmparo Alvarez-ValdésJosé R. MasaguerM. Carmen Navarro-Ranninger...
The effects of weak donor ligands CH3CN, dmso, dmf, thf, the sterically hindered ligand 2-methylimidazole (2-MeIm) and anionic ligands CN, Cl, Br, on the axial ligation reactions of trans-FeN4L(CO) complexes are described (N4=the tetradentate macrocyclic ligand bis-difluoro(dimethylglyoxi...
以cyclohexylamine 1a为例:cyclohexylamine 1a (in MeCN, at r.t.)与Boc2O(1.5 equiv)/DMAP (0.1 equiv)得到N-Boc 衍生物,反应的主副产物随着温度和溶剂的不同而改变。以催化剂N-methylimidazole(MeIm)代替DMAP的实验,cyclohexylamine 1a与Boc2O反应只生成N-Boc化合物2a的单一产物 (Table 1)。 Experimental P...
Very High-Field Magnetization and Intermolecular Interactions:Application to {[tmen(2-MeIm)Cu]2(C2O4)}(PF6)2 (tmen = N,N,N',N'-Tetramethylethylenediamine, 2-MeIm = 2-Methylimidazole) 方程式-SCI3 2024-11-22 14:58 0 0 Tris(acetato)bis(N,N,N',N'-tetramethylethylenediamine)(urea)...
以cyclohexylamine 1a为例:cyclohexylamine 1a (in MeCN, at r.t.)与Boc2O(1.5 equiv)/DMAP (0.1 equiv)得到N-Boc 衍生物,反应的主副产物随着温度和溶剂的不同而改变。以催化剂N-methylimidazole(MeIm)代替DMAP的实验,cyclohexylamine 1a与Boc2O反应只生成N-Boc化合物2a的单一产物 (Table 1)。
(新抗肿瘤转移抑制剂,A:该系列中的第一个化合物,trans。[RuCl4(DMSO)(imidazole)][Himidazole])衍生物略比 相应的NAMI衍生物稳定. 关键词 钉化合物;2一甲基咪唑;N-乙基咪唑;抗转移;水解动力学;稳定性 InfluenceofLigandStructureontheHydrolysisandStabilityofNAMI DerivativesContaining2-MethylimidazoleandN-Ethyl...
Reduction of aluminium(III) and gallium(III) chloride phthalocyanines (Pc) in the presence of N-methylimidazole (MeIm) by sodium fluorenone ketyl allows the dissolution of phthalocyanines. Slow mixing with n-hexane crystallizes formally neutral compounds 0·MeIm (1) and 0·2C6H4Cl2 (2), ...
A new series of N-phthaloylglycineate (N-phthgly) ternary complexes of cobalt(II) and nickel(II) with imidazole (imi), N-methylimidazole (mimi) and 2,2′-b... LH Abdel-Rahman - 《Transition Metal Chemistry》 被引量: 8发表: 2006年 多酸晶体的合成及其在...
Electronic structure of low-spin ferric chlorins: characterization of bis(1-methylimidazole)(meso-tetraphenylchlorinato)iron(III) triflate The synthesis and characterization of the trifluoromethanesulfonato derivative of bis(1-methylimidazole)tetrakis(phenyl)chlorinatoiron(III) [Fe(TPC)(1-MeIm... Gér...
The reaction of [CpMo(CO)2]2 with 2-mercapto-1-methylimidazole resulted in a mixture of mononuclear CpMo(CO)2(κ2-C4H5N2S) and trinuclear [(CpMo)3(μ-CO)2(μ-S)(μ-κ2-C4H5N2S)(μ3-S)], (169) (Scheme 63). Reacting [{CpMo(CO)2}2] with 2-mercaptobenzothiazole similarly ...