2-Methylimidazole palladium(II) complexesThe preparation of two new tetracoordinated complexes of palladium(II) with 2-methylimidazole, 2-MeIm, and chloride as ligands is described.doi:10.1007/BF00619475M José CamazónAmparo Alvarez-ValdésJosé R. MasaguerM. Carmen Navarro-Ranninger...
(DMSO)(2-MeIm)Na•2DMSO(2-MeIm=2-methylimidazole,Compd.1)and trans-[RuCl 4 (DMSO)(N-EtIm)]Na•2DMSO(N-EtIm=N-ethylimidazole,Compd.2)wereprepared.Their hydrolyticmechanism-kineticsinpH7.40/5.00buffersolutionandstabilityinphysiologicalconditionwere ...
以cyclohexylamine 1a为例:cyclohexylamine 1a (in MeCN, at r.t.)与Boc2O(1.5 equiv)/DMAP (0.1 equiv)得到N-Boc 衍生物,反应的主副产物随着温度和溶剂的不同而改变。以催化剂N-methylimidazole(MeIm)代替DMAP的实验,cyclohexylamine 1a与Boc2O反应只生成N-Boc化合物2a的单一产物 (Table 1)。 Experimental P...
以cyclohexylamine 1a为例:cyclohexylamine 1a (in MeCN, at r.t.)与Boc2O(1.5 equiv)/DMAP (0.1 equiv)得到N-Boc 衍生物,反应的主副产物随着温度和溶剂的不同而改变。以催化剂N-methylimidazole(MeIm)代替DMAP的实验,cyclohexylamine 1a与Boc2O反应只生成N-Boc化合物2a的单一产物 (Table 1)。 Boc2O/DMAP...
The effects of weak donor ligands CH3CN, dmso, dmf, thf, the sterically hindered ligand 2-methylimidazole (2-MeIm) and anionic ligands CN, Cl, Br, on the axial ligation reactions of trans-FeN4L(CO) complexes are described (N4=the tetradentate macrocyclic ligand bis-difluoro(dimethylglyoxi...
·-methylimidazole C1leIIlical 印卵缸脚j Technology Graduate Advisor:Ph Student:Guang-fuSong D.Qian-rongPeng, Ontheeffectofinternational taste consunler’staste cigarettesbeingchanged,the isturned into tar harmful andless gradllallyhighflavor,low allefforttoreducetar harm anddecreasetoeOllSUiIter’s...
Reduction of aluminium(III) and gallium(III) chloride phthalocyanines (Pc) in the presence of N-methylimidazole (MeIm) by sodium fluorenone ketyl allows the dissolution of phthalocyanines. Slow mixing with n-hexane crystallizes formally neutral compounds 0·MeIm (1) and 0·2C6H4Cl2 (2), ...
Te-Fe-Cu-L (L = NHC or N-alkyl imidazole) 系統利用 [TeFe3(CO)9]2─,[Cu(MeCN)4][BF4] 和 1-methylimidazole (MeIm) 或在其骨架上修飾有苯環之 1-methylbenzimidaz... 簡立慈 - 《臺灣師範大學化學系學位論文》 被引量: 0发表: 2012年 ...
Synthesis and crystal structure of Li[(O-4,6-di-tBu-C6H2)2(CH2)]2Y[MeIm]2(THF)2 (MeIm = N-Methylimidazole). The title complex Li[(O-4,6-di-tBu-C6H2)2(CH2)]2Y[MeIm]2(...
The reaction of [CpMo(CO)2]2 with 2-mercapto-1-methylimidazole resulted in a mixture of mononuclear CpMo(CO)2(κ2-C4H5N2S) and trinuclear [(CpMo)3(μ-CO)2(μ-S)(μ-κ2-C4H5N2S)(μ3-S)], (169) (Scheme 63). Reacting [{CpMo(CO)2}2] with 2-mercaptobenzothiazole similarly ...