Kraft et al., Mechanism of Vinylic and Allylic Carbon-Fluorine Bond . . . , Journal of Am. Chem. Soc., vol. 124, No. 29, 2002, pp. 8681-8689.Kraft, Bradley M. et al., “Mechanism of Vinylic and Allylic Carbon-Fluorine Bond Activation of Non-Perfluorinated Olefins Using Cp*2Zr...
ChemInform Abstract: ALLYLIC VS. VINYLIC DEPROTONATION REACTIONS OF CYCLIC VINYL ETHERS. 7-LITHIO-2,3,4,5-TETRAHYDROOXEPIN: SYNTHESIS AND CARBON-13 NMR SPECTRUMmulti‐membered N‐heterocyclesNo abstract is available for this article.doi:10.1002/chin.198252263...
palladiummigrationA unique transformation to realize the allylic amination from vinylic bromides was described and an unexpected C-Pd migration was observed from sp² carbon to adjacent allylic sp³ carbon initiated from vinyl bromide. Various 3-aryl-2-bromopropenes and secondary amines were ...
carbon to adjacent allylic sp carbon initiated from vinyl bromide. Various 3-aryl-2-bromopropenes and secondary amines were surveyed and the allyl amination products were obtained in moderate isolated yields. The primary amine was not fit for this transformation. Mechanistic studies indicate that this...
Reactivity of allylic and vinylic silanes, germanes, stannanes and plumbanes toward S H 2′ or S H 2 substitution by carbon- or heteroatom-centered free radicalssubstitution reactionsCompounds of the type CH 2 CHCH 2 MR 3 and E -PhCH CHMR 3 (M Si, Ge, Sn, Pb) were allowed to ...
THE INFLUENCE OF HETEROATOMS IN ALLYLIC AND VINYLIC CARBANIONS: SYNTHESES, REACTIONS, PRODUCT CHEMISTRY AND CARBON-13 NMR STUDY.Isomerization of N,N-dimethylallylamine leads to formation of trans-N,N-dimethylpropenylamine when the isomerization is completed using conditions which allow equilibration to ...