centre of splittingdiffuse charge model/ A3000 Atomic and molecular physicsThe electrostatic point charge model of the ligand field theory is extended by representing each ligand by 2635 points uniformly distributed at the position of the ligands. Application to a square planar, trigonal bipyramidal ...
Single-crystal polarized spectra have been recorded for a high-spin trigonal-bipyramidal CoNS3Br chromophore. These spectra as well as those of the chromophores CoNP3Br and CoNN3Br have been interpreted on the basis of ligand field and angular overlap parameters. These parameters, which have been...
ChemInform Abstract: Redirected Ligand-Field Analysis. Part 2. Asymmetric Chelation in Trigonal-Bipyramidal Copper(II) Complexesstructure (organic substancesNo abstract is available for this article.doi:10.1002/chin.198513053DEETH R. J.GERLOCH M....
A trigonal-bipyramidal oxorhenium(V) complex with a bidentate nitrogen-donor ligand 来自 Semantic Scholar 喜欢 0 阅读量: 25 作者:Irvin Booysen &,Peter Mayer 摘要: The oxorhenium(V) complex [ReO(Hapb)(apb)] (1) (H2apb =2-(2-aminophenyl)-1-benzimidazole) was prepared by reaction of ...
Lu TT, Yang LB, Liaw WF (2010) Trigonal bipyramidal {Fe(NO)}7 complex [(NO)Fe(SC9H6N)2] containing an equatorial nitrosyl ligand: the critical role of chelating ligands in regulating the geometry and transformation of mononitrosyl iron complex (MNIC). J Chin Chem Soc 57:909...
ChemInform Abstract: LIGAND FIELD INTERPRETATION OF HIGH-SPIN TRIGONAL-BIPYRAMIDAL COBALT(II) COMPLEXESorgano-cobalt compoundselectron spectra, ESCA (organic substances)doi:10.1002/chin.197525387I. BERTINID. GATTESCHIA. SCOZZAFAVAChemischer Informationsdienst...
ChemInform Abstract: LIGAND FIELD INTERPRETATION OF HIGH-SPIN TRIGONAL-BIPYRAMIDAL COBALT(II) COMPLEXES I Bertini,D Gatteschi,A Scozzafava - 《Chemischer Informationsdienst》 被引量: 5发表: 1975年 ChemInform Abstract: LIGAND FIELD INTERPRETATION OF HIGH-SPIN TRIGONAL-BIPYRAMIDAL COBALT(II) COMPLEXES I....
trigonal-bipyramidalamidecrystal structureThe oxorhenium(V) complex [ReO(Hapb)(apb)] (1) (H2apb =2-(2-aminophenyl)-1-benzimidazole) was prepared by reaction of trans-[ReO2(py)4]Cl with a twofold molar amount of H2apb. The complex was characterized by spectroscopy and X-ray ...
Trigonal-Bipyramidal Geometry in a Cobalt(II) Complex with an Unsymmetrical Tripodal Ligand 来自 掌桥科研 喜欢 0 阅读量: 22 作者:JW Lim,M Mikuriya,H Sakiyama 摘要: yA cobalt(II) complex with bis[2-(3,5-dimethylpyrazol-1-yl)ethyl][(pyrazol-1-yl)methyl]amine (bppa), [CoCl(bppa)][B...
Complex 1 displays trigonal-bipyramidal geometry with phosphine ligands occupying axial sites. The technetium-aryldiazenido moieties are nearly equivalent, with Tc-N-N bond angles of 166.2 (6) and 170.7 (7)掳 and multiple bonding throughout. The chloride ligand occupies the remaining equatorial......