crystal field analysisELECTRON-STRUCTUREORGANOMETALLIC COMPLEXESF-ELEMENTSLANTHANIDESThe absorption spectrum of pseudo (psi) trigonal planar Nd(eta(5)-C5Me4H)(3) (1) has been measured at room and low temperatures. From the spectra obtained, a truncated crystal field (CF) splitting pattern could be...
A new high-order perturbation formula for the zero-field splitting of the 4A2 ground state of d3,7 ions in a trigonal field is derived on the basis of the weak-field approximation. The formula obtained is shown to be a good approximation for the cases where the cubic field parameter Dq...
Zero-Field Splitting and g Factors for d2 Ions in Trigonally Distorted Cubic Crystal FieldsThe project supported by National Natural Science Foundation of China, Grant No. 19744001. 来自 IOP 喜欢 0 阅读量: 17 作者:D Ma,J Chen,X Ma,Y Liu ...
Zero-field splitting (ZFS) parameters of benzene, triphenylene, and coronene molecules in their lowest and second excited triplet states are calculated from the electron spin-spin interaction using semi-empirical self-consistentfield 蟺-... Higuchi,Jiro - 《Bulletin of the Chemical Society of Japan...
centre of splittingdiffuse charge model/ A3000 Atomic and molecular physicsThe electrostatic point charge model of the ligand field theory is extended by representing each ligand by 2635 points uniformly distributed at the position of the ligands. Application to a square planar, trigonal bipyramidal ...