thiol-ene chemistrythiol-ene reactionsSummary Thiol-ene reactions are most commonly photoinitiated and generally utilize a stoichiometric reaction mixture of thiols and enes. The radical initiated thiol-ene reaction is unique in that it is the only known radical step growth polymerization. Thiol-ene ...
Thiol-yne chemistry: A powerful tool for creating highly functional materials. Hoogenboom,Richard. Angewandte Chemie - International Edition . 2010Hoogenboom R.Thiol-ene chemistry:A powerful tool forcreating highly functional materials.Angewandte ChemieInternational Edition. 2010...
His work on thiol–ene chemistry and his passion and enthusiasm for that chemistry was legendary. He was a dedicated husband, father, and advisor, and a brilliant scientist who is missed by all who knew him. Thiol–Ene Reaction Angewandte Chemie 1541 Angew. Chem. Int. Ed. 2010, 49, 154...
The influence of alkene functionality on the energetics and kinetics of radical initiated thiol-ene click chemistry has been studied computationally at the CBS-QB3 level. Relative energetics (ΔH°, ΔH(++), ΔG°, ΔG(++)) have been determined for all stationary points along the step-growth...
Thiol-ene click chemistry. 来自 万方 喜欢 0 阅读量: 904 作者: Charles?E. Hoyle,Christopher?N. Bowman 摘要: Following Sharpless visionary characterization of several idealized reactions as click reactions, the materials science and synthetic chemistry communities have pursued numerous routes toward the ...
By extending our previously-reported thiol-ene click chemistry to functionalize PCOE with three different acid-terminated linear pendants, we further advance the strategy for polymer-to-polymer upcycling by dehydrogenation then functionalization of polyolefins. In previous work, we used thiol-ene click ch...
Photoinitiated thiol–ene chemistry is well-suited as an alternative and recently has found utility in biofabrication.5,19,28 The photoinitiated thiol–ene can be highly efficient, orthogonal to other chemistries, and tolerant to oxygen and can form more homogeneous (step-growth) hydrogel networks ...
thiol–ene click chemistryFunctionalized pyrrolidinium compounds, 3-((2-hydroxyethylthio)methyl)-1,1,4-trimethylpyrrolidinium and 3-((2-carboxyethylthio)methyl)-1,1,4-trimethylpyrrolidinium chlorides, are prepared from N,N-diallyl-N,N-dimethylammonium chloride by radical thiol-ene addition and are ...
For the first time thiol-ene click chemistry was used for the immobilization of Ru(bpy) 3 2+. The immobilization method is simple, fast, and efficient. The ECL sensor exhibited excellent stability in organic solvent and good reproducibility.关键词: Electrochemiluminescence sensor Ru(bpy) 3 2 Cl...
Thiol‐ene click chemistry was employed to form microspheres with sugar groups with high bioactivity and efficient binding of Concanavalin A. Two systems w... W Gu,G Chen,MH Stenzel - 《Journal of Polymer Science Part A Polymer Chemistry》 被引量: 120发表: 2009年 Synthesis of (Bio)‐Degrada...