Charles E. Hoyle ProfChristopher N. Bowman ProfAngewandte Chemie International Edition
thiol–enereactionFollowing Sharpless′ visionary characterization of several idealized reactions as click reactions, the materials science and synthetic chemistry communities have pursued numerous routes toward the identification and implementation of these click reactions. Herein, we review the radical‐...
Thiol-ene “click” reactions and recent applications in polymer and materials synthesis 1.IntroductionThe introduction and development of the “click” approach to the design and preparation of complex, highly functional molecules, a... AB Lowe - 《Polymer Chemistry》 被引量: 0发表: 2009年 Multi...
Thiol-ene click chemistry. 来自 万方 喜欢 0 阅读量: 904 作者: Charles?E. Hoyle,Christopher?N. Bowman 摘要: Following Sharpless visionary characterization of several idealized reactions as click reactions, the materials science and synthetic chemistry communities have pursued numerous routes toward the ...
thiol–ene click chemistryFunctionalized pyrrolidinium compounds, 3-((2-hydroxyethylthio)methyl)-1,1,4-trimethylpyrrolidinium and 3-((2-carboxyethylthio)methyl)-1,1,4-trimethylpyrrolidinium chlorides, are prepared from N,N-diallyl-N,N-dimethylammonium chloride by radical thiol-ene addition and are ...
反应体系要除氧;巯基原料有没有变质等。另外,你说的做不出来是指没有得到目标产物,还是说产率较低,...
The influence of alkene functionality on the energetics and kinetics of radical initiated thiol-ene click chemistry has been studied computationally at the CBS-QB3 level. Relative energetics (ΔH°, ΔH(++), ΔG°, ΔG(++)) have been determined for all stationary points along the step-growth...
For the first time thiol-ene click chemistry was used for the immobilization of Ru(bpy) 3 2+. The immobilization method is simple, fast, and efficient. The ECL sensor exhibited excellent stability in organic solvent and good reproducibility.关键词: Electrochemiluminescence sensor Ru(bpy) 3 2 C...
这个反应按道理应该很容易进行,可是我一直做不出来,不知道原因,求指导: [box=white]1,双键、巯基、引发剂的比例是多少?我现在巯基与双键的比例约为1.5:1,引发剂安息香乙醚,AIBN,2959都试了,用量为1%wt。 2,关于三乙胺催化体系,不能用于水相吧? 3,体系必须是均相吗?异相反应可不可行?[/box] 求此方向大神...
chemistry communities have pursued numerous routes toward the identification and implementation of these click reactions. Herein, we review the radical-mediated thiol–ene reaction as one such click reaction. This reaction has all the desirable features of a click reaction, being highly efficient, simpl...