A R. The thiol-ene (click) reaction for the synthesis of plant oil derived polymers. European Journal of Lipid Science and Technology, v. 115, n. 1, p. 41-54, 2013.Tu¨ru¨nc¸ O, Meier MA (2013) The thiol-ene (click) reaction for the synthesis of plant oil derived polymers....
Thiol–ene "click" chemistry has emerged as a powerful strategy to construct carbon–heteroatom (CS) bonds, which generally results in the formation of two regioisomers. To this end, the neutral ionic liquid [hmim]Br has been explored as a solvent cum catalyst for the synthesis of linear ...
This study is expected to create a promising avenue for thiol-ene click reactions in SDT and starvation therapy for cancer.缺氧的肿瘤微环境(TME)限制了声动力疗法(SDT)杀灭癌细胞的 效果, 而且癌细胞中过量的谷胱甘肽(GSH)进一步加剧了这种疗效限 制. 同时, 癌症饥饿疗法作为一种有前途的临床治疗手段已...
A novel mercaptotetrazole‐silica hybrid monolithic column was prepared for capillary liquid chromatography, in which the thiol‐end mercaptotetrazole was mixed with hydrolyzed γ‐methacryloxypropyltrimethoxysilane and tetramethyloxysilane for the co‐polycondensation and thiol‐ene click reaction in a one...
The thiol–ene click reaction in which thiyl radicals, generated by UV light, attack preferably electron-rich alkenes to form thioethers has proven a versatile methodology for bioconjugation (Scheme 1A) [38,39]. The concept that metal-coordinated thiolates can carry radical character and react ...
The ROS-responsive PEG-PTK-PEG triblock copolymers were synthesized by thiol-ene click reaction between the SH groups on the both ends of PTK and C=C end-capped m-PEG-acrylate (Fig. S1). The PTK was synthesized with a method adapted from a previous report [51]. Fig. 2 show the chara...
The mild and highly efficient thiol-ene click reaction has been used to construct a rotaxane incorporating dibenzo-24-crown-8 (DB24C8) and a dibenzylammonium-derived thread in high yield under the irradiation of UV light. A rotaxane containing a disulfide linkage in the macrocycle was also syn...
“Thiol-yne” click reaction has already been widely applied in synthesis and modification of new polymer structures or novel materials due to its specific features. However, in most studies, only chain-end strategy was employed when using the di-addition feature of thiol-yne reaction, thus the...
Nitrogen-phosphor skeleton epoxy-ended hyperbranched polymers (NPEHP-n) with a precisely controlled DB was synthesized by using the thiol-ene click reaction [21]. The effect of DB and content of the NPEHP-n on the particle sizes, rheological and mechanical (tensile, flexural and impact strength...
2012. Thiol–Ene Click Chemistry: Computational and Kinetic Analysis of the Influence ofAlkene Functionality. 1990. Polyaddition of dithiol compounds to divinyl compounds: Thekinetics of the model addition reaction of thiophenols to styrene... RH Pallen,C Sivertz - 《Canadian Journal of Chemistry...