alcohols (acyclic compounds)The reagents used to transform epoxides, alkenes and α,β-unsaturated carbonyl compounds into allylic alcohols are considered.doi:10.1002/chin.200504237A. K. BanerjeeCent. Chem., Venez. Sci. Res. Inst., Caracas 1020‐A, Venez.P. S. Poon...
doi:10.1002/chin.200543054Jean Le BrasDebabrata ChatterjeeJacques MuzartJohn Wiley & Sons, Ltd.ChemInformLe Bras, J., D. Chatterjee and J. Muzart, 2005. Asimpleone-potsynthesis of - alkoxyalcohols from alkenes. Tetrahedron Lett, 46(28): 4741-4743....
1.1 – Synthesis of Alcohols and Ethers1.1 – Synthesis of Alcohols and EthersAlcohols can be obtained from many other classes of compounds such as alkyl halides, amines, alkenes, epoxides and carbonyl compounds. The addition of nucleophiles to carbonyl compounds is a versatile and conv...
A new method for preparation of alcohols from olefins with molecular oxygen and phenylsilane by the use of bis(acetylacetonato)cobalt(ii). Chem. Lett. 18, 1071–1074 (1989). Google Scholar Daub, M. E., Prudhomme, J., Le Roch, K. & Vanderwal, C. D. Synthesis and potent ...
Asymmetric isomerization of allylic alcohols. Tetrahedron Lett. 56, 6159–6169 (2015). Article CAS Google Scholar Arai, N., Sato, K., Azuma, K. & Ohkuma, T. Enantioselective isomerization of primary allylic alcohols into chiral aldehydes with the tol-binap/dbapen/ruthenium(II) catalyst. ...
Hydroxylation of Alkenes ---Preparation of Alcohol--- ---Preparation of Halide--- 1. From Alcohols 2. Halogenation of Certain hydrocarbons 3. Addition of Hydrogen Halide to Alkenes 4. Addition of Halogen to Alkenes and Alkynes 5. Halide Exchange ---Preparation of Halide--- ---Preparation ...
The combination of diorganic diselenide and N-chlorosuccinimide promotes the allylic oxidation of alkenes to allyl chlorides via a process which does not involve free radicals (Scheme 5 (e))121 and combination of a diselenide with t-butyl hydroperoxide efficiently oxidizes alcohols to carbonyl ...
Carbene and photocatalyst-catalyzed decarboxylative radical coupling of carboxylic acids and acyl imidazoles to form ketones Article Open access 23 May 2022 Direct ketone synthesis from primary alcohols and alkenes enabled by a dual photo/cobalt catalysis Article Open access 09 August 2024 Upgrading...
alcohols from renewable starting materials. Admittedly, the product titres achieved in this proof-of-concept study are too low to be economically and environmentally attractive. Further work in our groups will focus on the expansion of this proof-of-concept experiments for synthetic application, ...
of a two step hydroformylation and subsequent hydrogenation step as a synthetic route to alcohols is discussed. Additional information regarding the use of a variety of tertiary-phosphine-ruthenium complexes in the catalytic hydroformylation of alkenes to aldehydes-particularly the dependence of conversion ...