Sign in to download full-size image Stilbene derivatives are reduced in dimethylformamide to the dihydrocompound and in a number of cases [6,18] the mechanism is known to involve accumulation of the radical-anion in solution. This disproportionates to the starting material and the dianion, which...
The oxidation mechanism of aliphatic secondary alcohols and alkanes to corresponding ketones and hydroperoxides using a laser flash photolysis technique was first studied by the Tanielian research team [122]. It was found that the reduced form of decatungstate (W10O325−) can be reoxidized to ...
For example, the mutation (I238Y) of a vanillyl alcohol oxidase located at a distance of 33 Å from the flavine–adenine dinucleotide in the active site cavity increased the turnover number for creosol, even though structural changes, which could account for the improvement, were not ...
Different proteins of different enzyme classes, which are heme, non-heme iron, or non-iron metal dependent and have different protein structures as well as different reaction mechanism are known to catalyze alkene cleavage reactions [3]. Specifically, an isoeugnol and trans-anethole oxygenase from...