engineer AuPd alloy particles (denoted as AuPd/SiO2), conceptually different from traditional methods for tuning optical absorption of plasmonic Au or AuPd particles, to manipulate light-harvesting ability of AuPd particles for highly selective and efficient photocatalytic Suzuki cross-coupling reactions. ...
此外,Y3Pd2催化剂经过20次循环之后无明显失活,实验和理论计算表明,该电子盐化合物晶格Pd活性中心具有很强的抗溶解和抗团聚特性,从而保证了其优异的催化稳定性。该工作近日以题为“Palladium-bearing intermetallic electride as efficient and stable catalyst for Suzuki cross-coupling reactions”发表在知名期刊Nature Co...
Cross-coupling reactions, and the Suzuki reaction in particular, are among the widely used synthetic methods for creating new C-C bonds to form more complex molecules from smaller molecules. In the Suzuki reaction, or Suzuki–Miyaura reaction, an organoboron compound, and an organohalide are cr...
5. Suzuki, A. In Metal-catalyzed Cross-coupling Reactions; Diederich, F.; Stang, P. J., Eds.; Wiley-VCH: Weinhein, Germany, 1998, 49–97. (Review). 6. Stanforth, S. P. Tetrahedron 1998, 54, 263-303. (Review). 7. Zapf, A. Coupling of Aryl and...
参考资料 Schilter, O., Vaucher, A., Schwaller, P., & Laino, T. (2023). Designing catalysts with deep generative models and computational data. A case study for Suzuki cross coupling reactions. Digital Discovery.
该工作近日以题为“Palladium-bearing intermetallic electride as efficient and stable catalyst for Suzuki cross-coupling reactions”发表在知名期刊Nature Communications上。 图文导读 图1Y3Pd2电子盐化合物的电子结构和晶体结构 (a) Y3Pd2的晶体结构图。
2) Suzuki cross-coupling reaction Suzuki交叉偶联反应 1. This dissertation mainly described two ligand-free cross-coupling protocols,including ligand-free palladium-catalyzed Suzuki cross-coupling reaction and copper-catalyzed Sonogashira cross-coupling reaction. 本论文主要围绕在无配体条件下钯催化的Suzuki...
5. Suzuki, A. In Metal-catalyzed Cross-coupling Reactions; Diederich, F.; Stang, P. J., Eds.; Wiley-VCH: Weinhein, Germany, 1998, 49–97. (Review). 6. Stanforth, S. P. Tetrahedron 1998, 54, 263-303. (Review). 7. Zapf, A. Coupling of Aryl and Alkyl Halides with Organoboron...
(4): 351-367351Suzuki Cross Coupling Reaction- A Review Sarbjeet Singh Gujral, Smriti Khatri * , Poornima Riyal, Vinod GahlotMaharaja Surajmal Institute of Pharmacy, Janakpuri, New Delhi, IndiaAddress for Correspondance: smriti_dua@yahoo.com ABSTRACT: Suzuki cross coupling reaction is one of the...
Also known as: Suzuki-Miyaura cross-couplingThe Suzuki cross-coupling reaction is the organic reaction of an organohalide with an organoborane to give the coupled product using a palladium catalyst and base. The mechanism begins with oxidative addition of the organohalide to the Pd(0) to form a...