Manuel Mora,C·esar Jim·enez-Sanchidri·an,,Jos·e Rafael Ruiz.Suzuki cross-coupling reactions over Pd(II)-hydrotalcite catalysts in water.Journal of Molecular Catalysis A Chemical. 2008Suzuki cross-coupling reactions over Pd(II)-hydrotalcite catalysts in water[J] . Manuel Mora,César Jiménez-...
The Suzuki–Miyaura cross-coupling (SMC) reaction is one of the reliable carbon–carbon bond forming processes, broadly applied in the synthesis of valuable compounds, such as pharmaceuticals1,2. A critical step in the SMC reaction is the transmetalation of organopalladium(II) species with organob...
1.12.7.2.2.(i) Coupling reactions Suzuki reactions, especially those friendly to the environment, that involve ultrasonic irradiation have been reviewed recently.107 Cravotto and co-workers carried out ligand-free Pd/C-catalyzed Suzuki cross- and homo-couplings in either water or DMF using high-...
以上的所有Pd配体都是厌氧的,因此反应必须在氮气,氩气等惰性气体下反应。 Strategic Applications of Named Reactions in Organic Synthesis, László Kürti and BarbaraCzakó, Suzuki cross-coupling, page 448 有些反应,如氯代芳烃的偶...
[2] Yonglei Zhou et al., A General Copper Catalytic System for Suzuki–Miyaura Cross-Coupling of Unactivated Secondary and Primary Alkyl Halides with Arylborons.J. Am. Chem. Soc.2023,145, 28146. [3] Akira Suzuki, Cross-Coupling Reactions Of Organoboranes: An Easy Way To Construct C-C ...
Strategic Applications of Named Reactions in Organic Synthesis, László Kürti and BarbaraCzakó,Suzuki cross-coupling, page 448 有些反应,如氯代芳烃的偶联反应,还需要另外一些高催化活性的配体的参与,它们具有的共性就是电负性较强和空间位阻大。这是因为电负性较强的配体是有利于氧化加成反应;空间位阻大的配体...
5. Suzuki, A. In Metal-catalyzed Cross-coupling Reactions; Diederich, F.; Stang, P. J., Eds.; Wiley-VCH: Weinhein, Germany, 1998, 49–97. (Review). 6. Stanforth, S. P. Tetrahedron 1998, 54, 263-303. (Review). 7. Zapf, A. Coupling of Aryl and...
Solvent Effect on Palladium-Catalyzed Cross-Coupling Reactions and Implications on the Active Catalytic Species Angew. Chem. Int. Ed. 2011, 50, 8192 –8195 https://doi.org/10.1002/anie.201101746 注:文中图片可能源于参考文献,若有侵权,请联系删除。
V.Ultrasound promoted Suzuki cross-coupling reactions in ionic liquid at ambient conditions. Chemical Communications . 2002Rajagopal, R.; Jarikote, V. D.; Srinivasan, K. V. Ultrasound promoted Suzuki cross-coupling reactions in ionic liquid at ambient conditions. Chem. Commun. 2002, 616-617....
参考资料 Schilter, O., Vaucher, A., Schwaller, P., & Laino, T. (2023). Designing catalysts with deep generative models and computational data. A case study for Suzuki cross coupling reactions. Digital Discovery. 发布于 2023-05-29 12:56・韩国 ...