Rh6(CO)16(NCMe)carbon monoxidechloroforminorganic synthesisS. P. TunikDepartment of Chemistry, St. Petersburg University, Universitetskii pr., 2, St. Petersburg, 198904, Russia.A. V. VlasovDepartment of Chemistry, St. Petersburg University, Universitetskii pr., 2, St. Petersburg, 198904, ...
A new one pot reaction of hydroformylation–cyclotrimerization of cyclopentene 1a and cyclohexene 1b was selectively catalyzed by Rh 6(CO) 16 and H 3PW 12O 40· xH 2O (HPA-W 12) in THF as a solvent at 40 atm (CO/H 2=1/1) to give 2,4,6-trisubstituted-1,3,5-trioxanes 3a an...
O-2-2 (×16)163.4 Rh+0+0 (×6)62.3 🛠️ Calculate Oxidation Numbers 指令 Enter the formula of a chemical compound to find the oxidation number of each element. A net ionic charge can be specified at the end of the compound between { and }. For example: ZnCl4{2-} or NH2NH3{...
The thermal decomposition of Rh6(CO)16 on α-aluminaThe thermal decomposition of Rh6(CO)16 on α-aluminaThe heating of Rh 6(CO) 16 absorbed on α-alumina to 400 °C in either He or h 2 gave primarily carbon monoxide resulting from the thermal decarbonylation of the cluster. A little...
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tion of [Rh6(CO)16] Carbonylation of [Rh(COD)N3]2 and [Rh(CO)2NCO]2; a new selective method for preparation of [Rh6(CO)16]Carbonylation of [Rh(COD)N3]2 and [Rh(CO)2NCO]2; a new selective method for preparation of [Rh6(CO)16]Carbonylation of [Rh(COD)N 3] 2 (COD = 1...
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Carbon and oxygen chemical shift tensors for bridging and terminal carbonyl ligands in Fe2(CO)9 and Rh6(CO)16 were calculated by sum-over-states density-functional perturbation theory (SOS-DFPT). Agreement with experimental 13C shift tensors is excellent, and 17O shift tensors are predicted....
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