Reversible Deactivation Radical Copolymerization: Synthesis of Copolymers with Controlled Unit SequenceFRAGMENTATION CHAIN-TRANSFERGLASS-TRANSITION TEMPERATUREN-BUTYL ACRYLATEAMPHIPHILIC GRADIENT COPOLYMERSMETHACRYLIC MULTIBLOCK COPOLYMERSENZYMATIC MONOMER TRANSFORMATIONLIVING ANIONIC COPOLYMERIZATION...
Reversible Deactivation Radical Polymerisation is a beautiful name from the viewpoint of pedantic accuracy, but it does not exactly roll off the tongue. When these reactions were first discovered in the 1980s and 90s, they were given the more evocative name of ‘Living Radical Polymerisation’. T...
摘要: Reversible-deactivation radical polymerization (RDRP) processes, such as atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) polyme... 查看全部>>关键词: Reversible-deactivation radical polymerization (RDRP) Atom transfer radical polymerization Reversible ...
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4.DEFINITIONS OF RELATED TERMS4.1stable-radical-mediated polymerization, SRMPstable-free-radical-mediated polymerization, SFRPControlled reversible-deactivation radical polymerizationin which the deactivation involves reversiblecoupling with stable (persistent) free radicals.Note 1: This term embraces aminoxyl-...
merizationsis“reversible-deactivationradicalpolymerization”. Keywords:active-dormantequilibria;aminoxyl-mediated;AMRP;atomtransfer;ATRP; chainpolymerization;degenerativetransfer;DTRP;controlled;IUPACPolymerDivision; living;nitroxide-mediated;NMRP;radical;RAFT;reversible-deactivation;reversible-addi- ...
However, in the case of a radical process, such a method does not proceed well because the possibility of irreversible deactivation, such as radical-radical coupling termination, relatively increases, as the poly- merization proceeds to make the monomer concentration lower. Thus, the typical ...
Star glycopolymer with aggregation-induced emission effect was synthesized by reversible deactivation radical polymerization.The glycopolymer could act as fluorescent probe to detect boric acid in the range of 10–8000mg/mL.关键词: Aggregation-induced emission Glycopolymer Boric acid detection Fluorescent pro...
A. Ghadban, L. Albertin, Synthesis of glycopolymer architectures by reversible- deactivation radical polymerization, Polymers 5 (2013) 431-526.Ghadban, A.; Albertin, L. Synthesis of glycopolymer architectures by reversible-deactivation radical polymerization. Polymers 2013, 5, 431-526...
One of the challenges for brush synthesis for advanced bioinspired applications using surface-initiated reversible deactivation radical polymerization (SI-RDRP) is the understanding of the relevance of confinement on the reaction probabilities and specifically the role of termination reactions. The present wo...