Reversible Deactivation Radical Polymerisation is a beautiful name from the viewpoint of pedantic accuracy, but it does not exactly roll off the tongue. When these reactions were first discovered in the 1980s and 90s, they were given the more evocative name of ‘Living Radical Polymerisation’. T...
Two mathematical approaches for modeling of the kinetics and evolution of molar mass distributions in the reversible deactivation radical polymerization of vinyl monomers promoted by redox reaction with N﹉ydroxyphthalimide (NHPI) and xanthone (XT) are presented. In the first modeling approach, the ...
Keywords: active-dormant equilibria; aminoxyl-mediated; AMRP; atom transfer; ATRP;chain polymerization; degenerative transfer; DTRP; controlled; IUPAC Polymer Division;living; nitroxide-mediated; NMRP; radical; RAFT; reversible-deactivation; reversible-addi-tion-fragmentation chain transfer.CONTENTS1. ...
All reversible deactivation radical polymerization (RDRP) processes require a compromise between the rate of polymerization, which requires a high radical concentration, and retention of chain end functionality, which requires a low radi... N Ballard,JM Asua - 《Acs Macro Letters》 被引量: 0发表:...
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Reversible-Deactivation Radical Polymerization in the Presence of Metallic Copper. Comproportionation–Disproportionation Equilibria and Kinetics This article is the first in a series of papers, describing reversible-deactivation radical polymerization (RDRP) in the presence of metallic copper. The a... W...
reversible deactivation radical polymerizationsustainabilityThe recent focus of media and governments on renewability, green chemistry, and circular economy has led to a surge in the synthesis of renewable monomers and polymers. In this review, focussing on renewable monomers for reversible deactivation ...
This study examined the kinetics of copolymerization of two different simple model monomers, methyl methacrylate (MMA), and ethyl methacrylate (EMA), via Cu(0)-mediated reversible deactivation radical polymerization (RDRP), where the reactivities of MMA and EMA are expected to be nearly equal, and...
merizationsis“reversible-deactivationradicalpolymerization”. Keywords:active-dormantequilibria;aminoxyl-mediated;AMRP;atomtransfer;ATRP; chainpolymerization;degenerativetransfer;DTRP;controlled;IUPACPolymerDivision; living;nitroxide-mediated;NMRP;radical;RAFT;reversible-deactivation;reversible-addi- ...
Bert Klumperman1 Introduction to reversible deactivationradical polymerization1.1 IntroductionRadical polymerization is among the oldest techniques used for polymer synthesis.It is a typical example of a chain growth reaction in which the active center ata growing chain end is an unpaired electron or radic...